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Properties ofSrMO 3-δ(M=Fe,Co) as oxygen electrodes in alkaline solution
Authors:Y Takeda  R Kanno  T Kondo  O Yamamoto  H Taguchi  M Shimada  M Koizumi
Affiliation:(1) Department of Chemistry, Faculty of Engineering, Mie University, 514 Tsu, Japan;(2) Osaka Prefectural Industrial Research Institute, Nishi-ku, 550 Osaka, Japan;(3) The Institute of Scientific and Industrial Research, Osaka University, 565 Osaka, Japan
Abstract:Strontium ferrates and cobaltates with compositions SrFeO3-delta (0.06lesdeltales0.40) and SrCoO3-delta (0.04lesdeltales0.30) were synthesized. The dependence of the oxygen electrode properties on the delta value was examined in 1 mol dm–3 KOH solution. In the SrFeO3-delta series, the samples with 0.24<delta<0.29, showed the highest activity in both oxygen evolution and reduction reactions. In contrast, no strong dependence on the delta value was observed in SrCoO3-delta, which also showed a high catalytic activity for oxygen evolution.
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