| 氮杂环卡宾前体的合成 |
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| 引用本文： | 王磊,迟兴宝.氮杂环卡宾前体的合成[J].化工时刊,2012,26(3):21-22,25. |
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| 作者姓名： | 王磊 迟兴宝 |
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| 作者单位： | 淮北师范大学,安徽淮北,235000 |
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| 摘 要： | 利用三（2-氯乙基）胺tris（2-chloroethyl）amine]和N-乙基苯并咪唑的亲核反应,成功的合成了新颖的氮杂环卡宾前体tris-2-（3-alkylmethylbenzimidazolium-1-yl）ethyl]amine trichlorideH3 TIEtNR]-（Cl）3（R-Et）},再进行离子交换得到{tris-2-（3-alkylmethylbenzimidazolium-1-yl）ethyl]amine trichlorideH3 TIEtNR]-（PF6）3（REt）}。该化合物通过了核磁验证。
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| 关 键 词： | 氮杂环卡宾 前体 合成 |
Syntheis of N-Heterocyclic Carbene (NHC) Predecessor |
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| Wang Lei
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Chi Xingbao.Syntheis of N-Heterocyclic Carbene (NHC) Predecessor[J].Chemical Industry Times,2012,26(3):21-22,25. |
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| Authors: | Wang Lei Chi Xingbao |
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| Affiliation: | Wang Lei Chi Xingbao(School of Chemistry and Material Science,Huaibei Normal University,Huaibei,Anhui,235000) |
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| Abstract: | N-Heterocyclic Carbene(NHC) Predecessor:{tris-2-(3-alkylmethylbenzimidazolium-1-yl)ethyl]amine trichloride H3 TIEtNR]-(Cl)3(R=Et)}was successfully synthesized by Tris(2-chloroethyl)amine and N-Etthylbenzimidazole of nucleophilic reaction.{Tris-2-(3-alkylmethylbenzimidazolium-1-yl)ethyl]amine trichloride H3 TIEtNR]-(PF6)3(R=Et)}was obtained by ion exchange.The compound was verified by the NMR. |
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| Keywords: | N-heterocyclic carbene predecessor synthesis |
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