| 不对称酰胺基卟啉的合成及表征 |
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| 引用本文： | 王瑛,庄长福,张加研,秦永剑,师同顺.不对称酰胺基卟啉的合成及表征[J].广州化工,2012(1):43-44,49. |
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| 作者姓名： | 王瑛 庄长福 张加研 秦永剑 师同顺 |
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| 作者单位： | [1]西南林业大学材料工程学院,云南昆明650224 [2]吉林大学化学学院,吉林长春130023 |
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| 基金项目： | 云南省教育厅科学科研基金（2010Z040）; 西南林业大学重点学科建设项目（XKX200907）资助 |
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| 摘 要： | 通过5-（4-氨基）苯基-10,152,0-三苯基卟啉（MATPP）与3-氰基苯甲酸在CH2Cl2中直接反应得到一种新型不对称酰胺基卟啉配体5-（4-3-氰基苯甲酸酰亚胺基）苯基-101,5,20-三苯基卟啉配体（CBTPPH2）,利用紫外-可见光谱、红外光谱、核磁共振氢谱、质谱、元素分析等测试方法对化合物的结构加以确认。
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| 关 键 词： | 卟啉 合成 表征 |
Preparation and Characterization of Unsymmetrical Imide Porphyrin |
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| WANG Ying,ZHUANG Chang-fu,ZHANG Jia-yan,QIN Yong-jian,SHI Tong-shun.Preparation and Characterization of Unsymmetrical Imide Porphyrin[J].GuangZhou Chemical Industry and Technology,2012(1):43-44,49. |
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| Authors: | WANG Ying ZHUANG Chang-fu ZHANG Jia-yan QIN Yong-jian SHI Tong-shun |
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| Affiliation: | 1 Institute of Material Engineering,Southwest Forestry University,Yunnan Kunming 650224; 2 College of Chemistry,Jilin University,Jilin Changchun 130023,China) |
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| Abstract: | An unsymmetrical imide porphyrin ligand,5-（4-cyanogenicimidephenyl） phenyl-10,15,20-triphenyl porphyrin（CBTPPH2） were synthesized by the reaction of the cyanogenic benzyl acid and 5-（4-aminophenyl）-10,15,20-triphenylporphyrin（MATPP） in CH2Cl2.The CBTPPH2 was characterized by means of UV-Vis spectra,mass spectra,elemental analyses,IR spectra and 1H NMR spectra. |
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| Keywords: | porphyrin synthesize characterization |
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