首页 | 官方网站   微博 | 高级检索  
     

表面接枝高分子季铵盐的纳米SiO2应用于抗菌塑料的制备
引用本文:吴远根,WANG Guang-Li,王广莉,张难,佟会,王啸,邱树毅.表面接枝高分子季铵盐的纳米SiO2应用于抗菌塑料的制备[J].塑料工业,2007,35(2):50-53,56.
作者姓名:吴远根  WANG Guang-Li  王广莉  张难  佟会  王啸  邱树毅
作者单位:1. 贵州省发酵工程与生物制药重点实验室,贵州,贵阳,550003;贵州大学化学工程学院,贵州,贵阳,550003
2. 贵州大学化学工程学院,贵州,贵阳,550003
3. 贵州省发酵工程与生物制药重点实验室,贵州,贵阳,550003
4. 贵州省发酵工程与生物制药重点实验室,贵州,贵阳,550003;贵州大学化学工程学院,贵州,贵阳,550003;国家复合改性聚合物材料工程技术研究中心,贵州,贵阳,550014
基金项目:国家自然科学基金;国家高技术研究发展计划(863计划);贵州省自然科学基金;贵州省知工办人才基金;贵州省教育厅科研项目;贵州遵义碱厂横向合作项目
摘    要:对表面接枝高分子季铵盐的纳米SiO2粉体进行检测,结果表明其热稳定性良好,对细菌的抗菌效果显著,抗菌性能与市售载银无机抗菌剂相当。将其添加到不同树脂中制备抗菌塑料,抗菌检测结果表明,用PE和PVC作为基材树脂制备的抗菌塑料的抗菌效果十分显著,其用于制备抗菌PE的最佳添加质量分数为2%。对制备的抗菌PE分别进行了自然条件放置和人工加速老化处理,抗菌检测结果表明,该塑料具备了良好的抗菌长效性和稳定性。

关 键 词:纳米SiO2  高分子  季铵盐  表面接枝  抗菌塑料  长效性
文章编号:1005-5770(2007)02-0050-02
修稿时间:2006-11-06

Preparation of Antimicrobial Plastics Containing Nano-meter SiO2 Grafted High-molecular Quaternary Ammonium Salt
WANG Guang-Li.Preparation of Antimicrobial Plastics Containing Nano-meter SiO2 Grafted High-molecular Quaternary Ammonium Salt[J].China Plastics Industry,2007,35(2):50-53,56.
Authors:WANG Guang-Li
Affiliation:1. Guizhou Provincial Key Lab. of Fermentation Eng. and Biopharmaey, Gniyang 550003, China; 2. School of Chemical Eng., Guizhou University, Guiyang 550003, China; 3. National Eng. Research Center for Compounding and Modification of Polymer Materials, Gniyang 550014, China
Abstract:The nano-meter SiO2 surface grafted by high-molecular-weight quaternary ammonium salt was tested, and the results showed the grafted nano-meter SiO2 had good thermal stability and superior antibacterial action, which was about the same with that of the commercial Ag+ -containing inorganic antimicrobial materials. The antimicrobial nano-meter SiO2 was applied to the preparation of antimicrobial plastics. The result of the antimicrobial tests showed the microbicidal action of antimicrobial plastics made from PE and PVC was superior. The optimum addition of the antimicrobial nano-meter SiO2 for the preparation of antimicrobial PE was 2%. The prepared PE was treated by means of accelerated aging and placement on natural conditions respectively, and the results showed the antimicrobial PE had good long-time bactericidal action and microbicidal stability.
Keywords:Nano-meter SiO2  High-molecular-weight  Quaternary Ammonium Salt  Surface-graft Graft Modification  Antimierobial Plastics  Long-time Bactericidal Activity
本文献已被 CNKI 维普 万方数据 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司    京ICP备09084417号-23

京公网安备 11010802026262号