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乙烯基三乙氧基硅烷改性丙烯酸乳液的研究
引用本文:刘玉欣,孟声,吕耀辉.乙烯基三乙氧基硅烷改性丙烯酸乳液的研究[J].上海涂料,2011,49(2):1-5.
作者姓名:刘玉欣  孟声  吕耀辉
作者单位:1. 装甲兵工程学院装备再制造技术国防科技重点实验室,北京,100072
2. 北京工业大学环境与能源工程学院,100022
摘    要:以丙烯酸酯、乙烯基硅烷为主要原料,以OP-10和十二烷基硫酸钠(SDS)为复合乳化剂,采用连续滴加法进行乳液聚合,制备了有机硅改性丙烯酸酯乳液。实验结果表明:当甲基丙烯酸甲酯(MMA)与丙烯酸丁酯(BA)的质量比为1.2~1.0、有机硅单体用量占单体质量分数的3%~10%、复合乳化剂(OP-10:SDS=3:1)占单体质量分数的4%。5%时,可制得性能良好的硅丙乳液。

关 键 词:丙烯酸酯  乙烯基三乙氧基硅烷  乳液聚合  硅丙乳液

Study on Vinyl Triethoxysilane Modified Acrylate Emulsion
LIU Yu-xin,MENG Sheng,LV Yao-hui.Study on Vinyl Triethoxysilane Modified Acrylate Emulsion[J].Shanghai Coatings,2011,49(2):1-5.
Authors:LIU Yu-xin  MENG Sheng  LV Yao-hui
Affiliation:LIU Yu-xin1,MENG Sheng2,LV Yao-hui1(1.National Key Laboratory for Remanufacturing,Academy of Armored Forces Engineering,Beijing,100072,China,2.College of Environmental and Energy Engineering,Beijing University of Technology,100022,China)
Abstract:The silicone modified acrylate emulsion was prepared by means of continuous dripping with acrylate and vinyl silane as main material,dodecyl sulfate and OP-10 as complex emulsifier.The experimental results showed when m(MMA)∶m(BA)=1.2~1.0,w(organosilicon monomer)=3%~10%,w(complex emulsifier)=4%~5%(OP-10∶SDS=3∶1),an emulsion of good properties can be obtained.
Keywords:acrylic ester  vinyl triethoxysilane  emulsion polymerization  silicone-acrylate emulsion  
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