| 甲醇制烃催化剂及其反应机理研究进展 |
| |
| 引用本文： | 黄晓昌,方奕文,乔晓辉.甲醇制烃催化剂及其反应机理研究进展[J].工业催化,2008,16(1):23-27. |
| |
| 作者姓名： | 黄晓昌 方奕文 乔晓辉 |
| |
| 作者单位： | 汕头大学工业催化研究室，广东 汕头 515063 |
| |
| 摘 要： | 综述了改性和非改性ZSM-5、β和SAPO-34等多种催化剂在甲醇制烃类物质中的应用。ZSM-5主要用于甲醇制汽油过程以及甲醇芳构化反应，甲醇在β沸石上主要转化成乙烯、丙烯、丙烷、异丁烷、六甲基苯和少量五甲基苯，而SAPO-34对乙烯和丙烯等低碳烯烃具有较高的选择性（90%）。总结了甲醇制烃机理的研究进展，主要包括初始C—C的形成以及烃池物种的研究,讨论了甲醇制烃催化剂及其研究方向。
|
| 关 键 词： | 催化剂工程 甲醇制烃 甲醇制烯烃 甲醇制芳香烃 甲醇制汽油 |
| 文章编号： | 1008-1143（2008）01-0023-05 |
| 收稿时间： | 2007-08-17 |
| 修稿时间： | 2007-09-25 |
Recent researches in the catalysts for conversion of methanol to hydrocarbons and the reaction mechanism |
| |
| HUANG Xiaochang,FANG Yiwen,QIAO Xiaohui.Recent researches in the catalysts for conversion of methanol to hydrocarbons and the reaction mechanism[J].Industrial Catalysis,2008,16(1):23-27. |
| |
| Authors: | HUANG Xiaochang FANG Yiwen QIAO Xiaohui |
| |
| Affiliation: | Institute of Applied Catalysis, Shantou University, Shantou 515063, Guangdong，China |
| |
| Abstract: | Application of modified or non-modified ZSM-5, β and SAPO-34 zeolite catalysts in conversion of methanol to hydrocarbons was reviewed. ZSM-5 is mainly used in methanol-to-gasoline and methanol-to-aromatics process; methanol can be converted over β zeolite to ethylene, propylene, propane, iso-butane, hexamethylbenzene and small amount of pentamethylbenzene; SAPO-34 is highly-selective to lower olefins. The reaction mechanisms for methanol-to-hydrocarbons reactions were reviewed, especially formation of initial carbon-carbon bond and hydrocarbon species. |
| |
| Keywords: | catalyst engineering methanol-to-hydrocarbons methanol-to-olefins methanol-to-aromatics methanol-to-gasoline zeolite catalyst mechanism |
| 本文献已被 维普 万方数据 等数据库收录！ |
| 点击此处可从《工业催化》浏览原始摘要信息 |
|
点击此处可从《工业催化》下载全文 |
