A high-throughput chaotic advection microreactor for preparation of uniform and aggregated barium sulfate nanoparticles |
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| Authors: | Hua Yang Shi-Xiao Wei Han Chen Lang Chen Chak-Tong Au Ting-Liang Xie Shuang-Feng Yin |
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| Affiliation: | 1. College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Hunan University, Changsha, China;2. College of Chemical Engineering, Fuzhou University, Fuzhou, China |
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| Abstract: | A high-throughput (105.5 g/h) passive four-stage asymmetric oscillating feedback microreactor using chaotic mixing mechanism was developed to prepare aggregated Barium sulfate (BaSO4) particles of high primary nanoparticle size uniformity. Three-dimensional unsteady simulations showed that chaotic mixing could be induced by three unique secondary flows (i.e., vortex, recirculation, and oscillation), and the fluid oscillation mechanism was examined in detail. Simulations and Villermaux–Dushman experiments indicate that almost complete mixing down to molecular level can be achieved and the prepared BaSO4 nanoparticles were with narrow primary particle size distribution (PSD) having geometric standard deviation, σg, less than 1.43 when the total volumetric flow rate Qtotal was larger than 10 ml/min. By selecting Qtotal and reactant concentrations, average primary particle size can be controlled from 23 to 109 nm as determined by microscopy. An average size of 26 nm with narrow primary PSD (σg = 1.22) could be achieved at Qtotal of 160 ml/min. |
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| Keywords: | BaSO4 nanoparticles chaotic convection fluid oscillation high-throughput passive oscillating feedback microreactor |
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