Room temperature blue-green photoluminescence of MCM-41, MCM-48 and SBA-15 mesoporous silicas in different conditions |
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Authors: | Ligang Gai Haihui Jiang Deliang Cui Qilong Wang |
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Affiliation: | aSchool of Chemical Engineering, Shandong Institute of Light Industry, Jinan 250353, People’s Republic of China;bState Key Lab of Crystal Materials, Shandong University, Jinan 250100, People’s Republic of China |
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Abstract: | The photoluminescence (PL) properties of siliceous MCM (MCM-41 and MCM-48) and SBA-15, no Na-containing MCM-41, and modified SBA-15 by silylation were comparatively investigated in dry and damp conditions, displaying the highest PL intensity of MCM-48. The PL intensity of MCM-41 is lower than that of SBA-15 in dry conditions, but reverse in damp conditions. In comparison with that of Na-containing MCM-41, the PL intensity of MCM-41 without Na+ is stronger. The PL intensity of modified SBA-15 by silylation is decreased in dry conditions, and however, against moisture and degradation in damp conditions. Twofold coordinated silicon centers in the tested samples are responsible for the blue-green bands at 440 nm. The shoulder peaks around 460–490 nm occurred in damp conditions are assigned to peroxy free radicals. |
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