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In situ compatibilization of polypropylene–polyethylene blends: a thermomechanical and spectroscopic study
Authors:Ch Tselios  D Bikiaris  V Maslis  C Panayiotou
Affiliation:

Department of Chemical Engineering, University of Thessaloniki, 54006 Thessaloniki, Greece

Abstract:Polypropylene (PP) and low density polyethylene (LDPE) were melt blended in proportions of 75/25, 50/50 and 25/75 w/w, respectively. Poly(propylene-g-maleic anhydride) (PP-g-MA) with 0.8 mol% maleic anhydride content and poly(ethylene-co-vinyl alcohol) (EVAL) with 7.5 mol% vinyl alcohol content were added at a 50/50 w/w proportion as in situ reactive compatibilizers. Four series of compatibilized blends were produced containing 2.5, 5, 10 and 20 wt% compatibilizer in the final blend. The compatibilization reaction was followed by a torque increase during mixing and by FTi.r. spectroscopy. A notable improvement in tensile strength, elongation at break and impact strength was observed for all blends after compatibilization and, in particular, for the blends containing 10 wt% compatibilizer. Scanning electron microscopy (SEM), aided by micro-Raman spectroscopy, was used for investigating the morphology of the blends.
Keywords:Polymer blends  Polypropylenes  Low density polyethylenes  Tensile strength  Impact testing  Morphology  Scanning electron microscopy  Fourier transform infrared spectroscopy  Blending  Raman spectroscopy  Compatibilization  Melt blending
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