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干燥方法对NiMgAl类水滑石催化性能的影响
引用本文:卓欧,唐富顺,阮乐,王跃,张凯琳.干燥方法对NiMgAl类水滑石催化性能的影响[J].化工技术与开发,2011,40(10):8-12.
作者姓名:卓欧  唐富顺  阮乐  王跃  张凯琳
作者单位:桂林理工大学化学与生物工程学院,广西桂林,541004
基金项目:广西科学研究与技术开发计划项目(桂科攻1114021-3-1)
摘    要:采用盐-碱法制备了NiMgA1类水滑石,考察了不同干燥方法对类水滑石衍生复合氧化物的催化性能的影响,并用XRD、TPR、TPD、TG-DSC和BET等对不同干燥方法所得类水滑石及衍生复合氧化物的晶相结构、表面性能和热稳定性等进行了表征.结果表明,微波干燥得到的样品具有相对较大的比表面积,较高的还原温度,较强的C02吸附...

关 键 词:水滑石  Ni催化剂  甲烷  重整

Effects of Different Drying Method on Catalytic Properties of NiMgAl Hydrotalcite-like
ZHUO Ou,TANG Fu-shun,RUAN Le,WANG Yue,ZHANG Kai-lin.Effects of Different Drying Method on Catalytic Properties of NiMgAl Hydrotalcite-like[J].Technology & Development of Chemical Industry,2011,40(10):8-12.
Authors:ZHUO Ou  TANG Fu-shun  RUAN Le  WANG Yue  ZHANG Kai-lin
Affiliation:(College of Chemistry and Bioengineering,Guilin University of Technology,Guilin 541004,China)
Abstract:NiMgAl hydrotalcites were synthesized by coprecipitation method,and the effects on the catalytic properties had been studied by different dying method.The hydrotalcites and derived mixed oxides were characterized by XRD,TPR,TPD,TG-DSC and BET.The results showed that the samples obtained by microwave drying had a relatively high surface area,a higher reduction temperature,an enhanced CO2 adsorption capacity,and the active component could form a strong interaction with the Mg/Al oxides.Besides,samples dryed by microwave had a better catalytic performance in CO2 reforming CH4,including improved catalytic activity and high stability.
Keywords:hydrotalcite  Ni catalyst  methane  reform
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