| TMB等与乙酰基酚酮缩合反应的研究 |
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| 引用本文： | 张宝田,高文涛,朴明珠.TMB等与乙酰基酚酮缩合反应的研究[J].化学与粘合,1995(3). |
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| 作者姓名： | 张宝田 高文涛 朴明珠 |
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| 作者单位： | 锦州师范学院化学系，牡丹江师范学院化学系 |
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| 摘 要： | 本文探讨了酚酮领域内的羟醛结合反应，３－乙酰基酚酮与ＴＭＢ、丁香醛、胡椒醛等取代醛反应分别生成３－（３，４，５－三甲氧基）肉桔酰基酚酮、３－（４－羟基－３，５－二甲氧基）肉桂酰基酚酮和３－（３，４亚甲－３，４－二氧基）肉桂基酚酮．与桂皮醛反应生成３－（５－苯基－２，４－戊二烯酰基）酚酮等四种尚未见文献报道的新化合物．其结构经红外光谱、核磁共振谱及元素分析得以证实．
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| 关 键 词： | 乙酰基酚酮，3，4，5－三甲氧基苯甲醛，缩合反应 |
Condensation Reaction of 3-Acetyltropolone with Aromatic Aldehydes(TMB) |
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| Zhang Baotian and Gao Wentao.Condensation Reaction of 3-Acetyltropolone with Aromatic Aldehydes(TMB)[J].Chemistry and Adhesion,1995(3). |
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| Authors: | Zhang Baotian and Gao Wentao |
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| Abstract: | Four stew Produdts was obtaind by aldol condensation reaction of 3-acetyltropolone with aromatid aldehydes suchas TMB,3,4-methylenedioxybenzaldenyde, 4-liydroxy-3,5-dimethoxybenza ldehyde and cinnamaldehyde in the presende of KOH.Their strudtures were don firmd by their.IR,H-NMR spectral analysis and elementary analysis. |
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| Keywords: | acetyltropolone aromatic aldehyde condensation reaction |
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