| 微波辐射促进H6P2W18O62/SiO2催化H2O2氧化环己酮合成己二酸 |
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| 引用本文： | 曹小华,严平,刘新强,徐常龙.微波辐射促进H6P2W18O62/SiO2催化H2O2氧化环己酮合成己二酸[J].合成纤维工业,2011,34(6):11-13. |
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| 作者姓名： | 曹小华 严平 刘新强 徐常龙 |
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| 作者单位： | 九江学院化学化工学院,江西九江,332005 |
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| 基金项目： | 国家自然科学基金，江西省自然科学基金，江西省教育厅科技资助项目，九江学院质量工程项目 |
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| 摘 要： | 在微波辐射作用下,以自制的磷钨酸/二氧化硅为催化剂,在无有机溶剂、相转移催化剂的情况下,用w(H202) 30％的H2O2氧化环己酮合成己二酸；通过正交实验和单因次实验探讨了各因素对反应的影响,确定了优化工艺条件.结果表明:最优化工艺为磷钨酸负载量30％,磷钨酸/二氧化硅用量1.20 g、草酸0.18g,H2O2 32...
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| 关 键 词： | 负载型 磷钨酸 己二酸 环己酮 微波 辐射 |
H2O2 oxidation of cyclohexanone to adipic acid catalyzed by H6P2W18O62/SiO2 under microwave irradiation |
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| Cao Xiaohua
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Yan Ping
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Liu Xinqiang
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Xu Changlong.H2O2 oxidation of cyclohexanone to adipic acid catalyzed by H6P2W18O62/SiO2 under microwave irradiation[J].China Synthetic Fiber Industry,2011,34(6):11-13. |
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| Authors: | Cao Xiaohua Yan Ping Liu Xinqiang Xu Changlong |
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| Abstract: | Adipic acid was synthesized by cyclohexanone oxidation with 30%w(H_2O_2) catalyzed with self-made phosphotungstic acid/silicon dioxide in absence of organic solvent and phase transfer catalyst under microwave irradiation.The influential factors on the reaction were discussed by orthogonal and simple fact experiments.And the optimal process conditions were decided. The results showed that the yield of adipic acid reached 73.24%under the conditions as followed:phosphotungstic acid loading 30%,1.20 g phosphotungstic acid/silicon dioxide,0.18 g oxalic acid,32.0 mL H_2O_2,reaction temperature 100℃,microwave power 400 W,reaction time 4.0 h;and the adipic acid yield was still 50.42%while repeatedly using the catalyst 5 times. |
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| Keywords: | supported phosphotungstic acid adipic acid cyclohexanone microwave irradiation |
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