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苯-马共聚物高碳醇酯(SMAA)降凝剂的制备及其性能研究
引用本文:李亮,龙小柱,李研,王长松,宗学军,周扬.苯-马共聚物高碳醇酯(SMAA)降凝剂的制备及其性能研究[J].当代化工,2011,40(1):25-29.
作者姓名:李亮  龙小柱  李研  王长松  宗学军  周扬
作者单位:沈阳化工大学化学工程学院;辽河油田曙光工程技术处;
基金项目:辽宁省教育厅高等学校科学研究基金项目(2009A591)
摘    要:苯乙烯与马来酸酐在引发剂下反应得到苯-马聚合物,再与混合高碳醇酯化得到目标产物SMAA,并通过单因素实验和正交实验研究了SMAA合成的最佳反应条件及对辽宁瑞达石油技术有限公司高凝原油的降凝效果.制备苯-马聚合物(SMA)的最佳工艺条件:n(马来酸酐)/n(苯乙烯)=1:2、聚合温度75 ℃、聚合时间4 h、引发剂用量0...

关 键 词:苯乙烯  马来酸酐  混合高碳醇  聚合  酯化  降凝剂

Synthesis of the Pour Point Depressant of Styrene-Maleic Anhydride Copolymer Methylacrylic Higher Alcohols Ester and Performance Research
LI Liang,LONG Xiao-zhu,LI Yan,WANG Chang-song,ZONG Xue-jun,ZHOU Yang.Synthesis of the Pour Point Depressant of Styrene-Maleic Anhydride Copolymer Methylacrylic Higher Alcohols Ester and Performance Research[J].Contemporary Chemical Industry,2011,40(1):25-29.
Authors:LI Liang  LONG Xiao-zhu  LI Yan  WANG Chang-song  ZONG Xue-jun  ZHOU Yang
Affiliation:LI Liang1,LONG Xiao-zhu1,LI Yan1,WANG Chang-song1,ZONG Xue-jun1,ZHOU Yang2(1.Shenyang University of Chemical Technology,Liaoning Shenyang 110142,China,2.PetroChina Liaohe Oilfield Company Shuguang Engineering Technology Department,Liaoning Panjin 124109,China)
Abstract:Styrene reacted with maleic anhydride under the initiator condition to prepare copolymer(SMA).Then,the copolymer reacted with mixed higher alcohols to gain the target product(SMAA).The optimal synthesis conditions of SMAA were studied by single factor and orthogonal experiment,and depression effect for high pour point crude from Liaoning Rita petroleum technology company was investigated.The results show that the best technological conditions of preparing SMA:molar ratio of maletic anhydride to styrene is 1...
Keywords:Styrene  Maleic anhydride  Mixture of higher alcohols  Polymerization  Esterification  Pour point depressant  
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