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烟酸脉冲镀银及镀层性能的实验室研究
引用本文:徐晶,郭永,胡双启,赵璐,李江,赵建国.烟酸脉冲镀银及镀层性能的实验室研究[J].电镀与涂饰,2010,29(5).
作者姓名:徐晶  郭永  胡双启  赵璐  李江  赵建国
作者单位:中北大学化工与环境学院,山西,太原,030051;山西大同大学应用化学研究所,山西,大同,037009
摘    要:研究了烟酸体系双脉冲镀银的工艺条件对镀层的沉积速率.外观质量、结合力、抗变色能力及表面形貌的影响.在最佳工艺条件下,与丁二酰亚胺镀银工艺进行了比较.结果表明,电流密度为0.25A/dm2、频率为1 000Hz、温度为25℃时,可获得光亮、抗变色能力好的镀层.与丁二酰亚胺体系得到的镀层相比较,烟酸体系镀层性能更优.镀层银晶为立方晶系.

关 键 词:镀银  烟酸  脉冲  沉积速率  抗变色  结合力

Laboratory study on nicotinic acid silver pulse electroplating and deposit properties
XU Jing,GUO Yong,HU Shuang-qi,ZHAO Lu,LI Jiang,ZHAO Jian-guo.Laboratory study on nicotinic acid silver pulse electroplating and deposit properties[J].Electroplating & Finishing,2010,29(5).
Authors:XU Jing  GUO Yong  HU Shuang-qi  ZHAO Lu  LI Jiang  ZHAO Jian-guo
Affiliation:XU Jing,GUO Yong,HU Shuang-qi,ZHAO Lu,LI Jiang,ZHAO Jian-guo College of Environmental and chemical Engineering,North University of China,Taiyuan 030051,China
Abstract:The effects of process conditions on the deposition rate,appearance,adhesion strength,anti-tarnish property and surface morphology of the silver coating obtained from a nicotinic acid bath by pulse reverse plating were studied.Under optimal conditions,the above-mentioned process was compared with the butanediimide silver plating process.The results showed that bright deposit with good anti-tarnish property can be obtained by the given pulse reverse process at a current density of 0.25 A/dm~2, frequency 1 00...
Keywords:silver electroplating  nicotinic acid  pulse  deposition rate  anti-tarnish  adhesion  
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