含能材料燃烧过程中热分解化学的研究进展

从模拟燃烧条件、组分相互作用、组分物理状态、分析测试技术等几方面介绍了含能材料燃烧过程中热分解化学研究近几年来的最新进展。着重介绍燃烧热分解中的基元反应对建立推进剂燃烧新型模型的重要性、氧化剂和黏合剂及催化剂之间的相互作用、氧化剂的黏度和相态变化对燃烧和热分解过程的影响。

Advance of Thermal Decomposition Chemistry of Energetic Materials under Combustion Condition

New advance of recent years in the investigation of thermal decomposition chemistry of energetic materials under combustion condition was reviewed. The contents consist of the thermal decomposition at simulated combustion condition, interaction of the components of energetic maerials, an influence of physical state on thermolysis and measurement techniques etc. The objects of study were remarked which are the great importance of elementray reaction of thermal decomposition to build combustion new model of propellants, the interactions of oxidants with adhesives and catalysts, and the influence of grain size and phase transition of the oxidants on the processes of combustion and decomposition.