| 不对称卟啉及其锌配合物的制备及电化学研究 |
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| 引用本文： | 王瑛,庄长福,张加研,吴春华,田珩,师同顺.不对称卟啉及其锌配合物的制备及电化学研究[J].化学试剂,2012,34(7):585-588. |
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| 作者姓名： | 王瑛 庄长福 张加研 吴春华 田珩 师同顺 |
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| 作者单位： | 1. 西南林业大学 材料工程学院,云南昆明,650224
2. 吉林大学 化学学院,吉林长春,130023 |
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| 基金项目： | 国家自然科学基金资助项目，云南省自然科学基金资助项目，云南省教育厅科学研究基金重点项目，西南林业大学重点学科建设资助项目 |
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| 摘 要： | 合成了新型5-(4-吡嗪甲酰亚胺基)苯基-10,15,20-三苯基卟啉配体(H2P)及其锌配合物(ZnP),并通过质谱、元素分析、紫外-可见光谱、核磁共振氢谱、红外光谱等测试方法对其结构加以确认。同时还研究了配体和配合物的拉曼和荧光光谱的变化,并对其进行了电化学性质的研究。研究表明,配体和配合物的拉曼光谱及荧光光谱都有很大区别,卟啉的电化学性质不仅与周边取代基性质有关,还受其共轭体系的电子离域程度影响。
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| 关 键 词： | 卟啉 配合物 荧光光谱 电化学 |
Preparation, spectroscopic and electrochemical property of an Unsymmetrical porphyrin and its Zn compound |
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| WANG Ying
,
ZHUANG Chang-fu
,
ZHANG Jia-yan
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WU Chun-hua
,
TIAN Heng
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SHI Tong-shun.Preparation, spectroscopic and electrochemical property of an Unsymmetrical porphyrin and its Zn compound[J].Chemical Reagents,2012,34(7):585-588. |
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| Authors: | WANG Ying ZHUANG Chang-fu ZHANG Jia-yan WU Chun-hua TIAN Heng SHI Tong-shun |
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| Affiliation: | 1.Institute of Material Engineering,Southwest Forestry University,Kunming 650224,China;2.College of Chemistry,Jilin University,Changchun 130023,China) |
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| Abstract: | The new 5-(4-pyrazinoicaminophenyl)-10,15,20-triphenylporphyrin ligand(H2P) and its compound(ZnP) have been synthesized and characterized by elemental analyses,UV-Vis,IR and 1HNMR spectroscopies.The cyclic voltammetry,Raman spectra and fluorescence spectra of H2P and ZnP were investigated.The results showed that Raman spectra and fluorescence spectra of H2P was different from ZnP.The electrochemical properties of the porphyrin were influenced by the linked substitutent and electron conjugative effect of porphyrin. |
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| Keywords: | porphyrin compound fluorescence spectra electrochemistry |
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