| TiB2在球磨中的氧化行为 |
| |
| 引用本文： | 黄飞,傅正义,王为民,王皓,王玉成,张金咏,张清杰.TiB2在球磨中的氧化行为[J].硅酸盐学报,2008,36(1):17-20. |
| |
| 作者姓名： | 黄飞 傅正义 王为民 王皓 王玉成 张金咏 张清杰 |
| |
| 作者单位： | 武汉理工大学,复合材料新技术国家重点实验室,武汉,430070 |
| |
| 基金项目： | 教育部重大培育和创新团队项目
,
湖北省创新研究群体科学基金 |
| |
| 摘 要： | 用行星球磨对TiB2原粉进行处理,并用X射线光电子能谱仪,X射线衍射仪,能量色散X射线荧光光谱仪等对TiB2在球磨过程中的氧化行为进行分析.结果表明:在室温下TiB2粉末存在表面氧化,而球磨加速TiB2粉末氧化,随着球磨时间的延长,TiB2粉末的氧化程度加大;酸洗及离心作用造成硼的流失,使B和Ti的摩尔比失调,最终形成TiO2和少量硼酸包覆TiB2结构;通过改变不同球磨工艺,发现湿磨加Ar保护工艺使TiB2被氧化程度明显降低.
|
| 关 键 词： | 二硼化钛 行星球磨 氧化 titanium diboride planetary ball-milling oxidation |
| 文章编号： | 0454-5648（2008）01-17-04 |
| 收稿时间： | 2007-06-19 |
| 修稿时间： | 2007-07-31 |
OXIDATION BEHAVIOR OF TiB2 DURING BALL-MILLING |
| |
| HUANG Fei,FU Zhengyi,WANG Weimin,WANG Hao,WANG Yucheng,ZHANG Jinyong,ZHANG Qingjie.OXIDATION BEHAVIOR OF TiB2 DURING BALL-MILLING[J].Journal of The Chinese Ceramic Society,2008,36(1):17-20. |
| |
| Authors: | HUANG Fei FU Zhengyi WANG Weimin WANG Hao WANG Yucheng ZHANG Jinyong ZHANG Qingjie |
| |
| Abstract: | TiB2 raw powders were treated by planetary ball-milling and the oxidation behavior was analyzed by X-ray photoelectron spectrometer, X-ray diffractometer, energy dispersive X-ray spectrometry. The results show that the surface of TiB2 powder was oxidized at room temperature, oxidation was accelerated during ball-milling and increased gradually with the increasing of ball-milling time. The molar ratio of B to Ti decreased because of the boron loss during acid cleaning and centrifugation. In the end, TiB2 powder was formed in coated with TiO2 and a small amount of H3BO3. When alcohol was used as medium and argon protection was adopted, the oxidation decreased obviously. |
| |
| Keywords: | titanium diboride planetary ball-milling oxidation |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
