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N80钢盐酸酸化缓蚀剂的合成及其缓蚀性能研究
引用本文:崔振东,樊利华,王维珍,高丽丽,侯相钰,吴东霞.N80钢盐酸酸化缓蚀剂的合成及其缓蚀性能研究[J].应用化工,2014(9):1595-1597.
作者姓名:崔振东  樊利华  王维珍  高丽丽  侯相钰  吴东霞
作者单位:国家海洋局天津海水淡化与综合利用研究所,天津,300192
基金项目:中央级公益性科研院所基本科研业务费专项资金项目(K-JBYWF-2012-G5);国家海洋局青年基金
摘    要:选用乙醇作为合成反应溶剂,喹啉和卤代烃经季铵化反应合成一种喹啉季铵盐盐酸酸化缓蚀剂YT-102。利用红外光谱仪对合成产物结构进行表征,采用静态失重法、极化曲线和交流阻抗等电化学方法对YT-102进行了缓蚀性能评价和电化学机理分析。结果表明,YT-102是以阳极抑制为主的混合抑制型缓蚀剂,可以有效抑制盐酸对N80碳钢的腐蚀,能够达到SY/T 5405—1996所规定的一级指标。

关 键 词:酸化  喹啉  季铵盐  缓蚀剂  盐酸

Synthesis and performance evaluation of a kind of quinoline quaternary ammonium salt as acidulate corrosion inhibitor for N80 steel
CUI Zhen-dong,FAN Li-hua,WANG Wei-zhen,GAO Li-li,HOU Xiang-yu,WU Dong-xia.Synthesis and performance evaluation of a kind of quinoline quaternary ammonium salt as acidulate corrosion inhibitor for N80 steel[J].Applied chemical industry,2014(9):1595-1597.
Authors:CUI Zhen-dong  FAN Li-hua  WANG Wei-zhen  GAO Li-li  HOU Xiang-yu  WU Dong-xia
Affiliation:( The Institute of Seawater Desalination and Multipurpose Utilization, SOA ( Tianjin), Tianjin 300192, China)
Abstract:Using ethyl alcohol as the solvent,a new quinoline quaternary ammonium acidification inhibitor was synthesized by quaternization of quinoline and alkyl halides. The synthesized inhibitor YT-102 was characterized with infrared spectrometer,static weight loss and electrochemical polarization curves and EIS for performance evaluation and electrochemical corrosion mechanism analysis. The results showed that YT-102 was mixed control type,could efficiently control the corrosion of N80 steel in hydrochloric acid,and could meet the first grade standard of SY/ T 5405-1996 at 60 ℃.
Keywords:acidification  quinoline  quaternary ammonium salt  corrosion inhibitor  hydrochloric acid
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