自制氧化铅电极降解苯酚的试验研究 |
| |
引用本文: | 金贻芳,于萍,罗运柏.自制氧化铅电极降解苯酚的试验研究[J].工业水处理,2016(5):55-59. |
| |
作者姓名: | 金贻芳 于萍 罗运柏 |
| |
作者单位: | 武汉大学化学与分子科学学院,湖北武汉,430000 |
| |
摘 要: | 以钛片为基底,Sn O2+Sb2O5为中间层,自制氧化铅电极用于苯酚的电化学降解。试验结果表明,自制电极具有良好的苯酚去除效果:在室温为15℃,电极间距为15 mm,电流密度为16 m A/cm2,苯酚溶液p H为6.3,导电介质Na2SO4浓度为0.25 mol/L时,电解300 m L初始质量浓度为100 mg/L的苯酚,4 h后去除率可达91.89%。研究降解过程中苯酚初始浓度、p H、导电介质、电流密度、电极间距等因素对苯酚降解过程的影响。在此基础上对苯酚降解影响较大的初始浓度、p H、电流密度3个因素优化,通过响应曲面分析交互影响和单因素影响,结果表明,三者交互影响不大,苯酚初始浓度影响最大,p H影响最小,与单因素影响分析结果吻合。
|
关 键 词: | 自制氧化铅电极 苯酚 电化学降解 响应曲面法 |
ExperimentaI study on the home-made Iead oxide eIectrode for the degradation of phenoI |
| |
Abstract: | Using titanium plate as substrate,and SnO2+Sb2O5 as an intermediary,the lead oxide electrode for electro-chemical degradation of phenol is made. The experimental results show that the homemade electrode has very good phenol removing effect. When the room temperature is 15℃,electrode spacing 15 mm,current density 16 mA/cm2, pH 6.3,and conductive medium Na2SO4 concentration 0.25 mol/L,300 mL of phenol,whose initial mass concentra-tion is 100 mg/L,is electrolyzed for 4 h,the removing rate can reach 91.89%. The influences of the factors,such as initial concentration of phenol,pH,conductive medium,current density,electrode spacing,etc. on the phenol degra-dation process are studied. On the basis of these results,the three factors that have more influences on phenol degra-dation,including initial concentration,pH and current density,are optimized,by response surface method,interac-tive influence and single-factor influence. The results show that the interactive influences of the three are not obvi-ous. The initial concentration of phenol has the largest influence,and pH has the least influence. It is in line with the analytical result of single factor influence. |
| |
Keywords: | homemade lead oxide electrode phenol electrochemical degradation response surface method |
本文献已被 CNKI 万方数据 等数据库收录! |
|