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铝空气电池用6061和7075铝合金阳极电化学性能
引用本文:杨亚刚,俞小花,张磊,史春阳,庄晓东,谢刚.铝空气电池用6061和7075铝合金阳极电化学性能[J].化工进展,2020,39(1):145-151.
作者姓名:杨亚刚  俞小花  张磊  史春阳  庄晓东  谢刚
作者单位:1. 昆明理工大学冶金与能源工程学院,云南 昆明 6500932. 昆明冶金研究院有限公司,云南 昆明 6505033. 共伴生有色金属资源加压湿法冶金技术国家重点实验室,云南 昆明650503
基金项目:云南省万人计划;国家自然科学基金
摘    要:研究了工业6061铝合金(6061)、航空7075铝合金(7075)和纯铝作为铝空气电池阳极材料的电化学性能,分析其作为阳极的可行性及适用环境。进行了阻抗、极化曲线和恒电流放电实验并进行了表面表征,计算了在40~120mA/cm2电流密度下连续恒流放电的阳极能量密度。用电子探针显微镜(EPMA)对电极表面形貌进行了研究,用波谱分析仪(WDS)进行表面分析。研究结果表明,合金元素在电池放电过程中会改变阳极的表面特性。6061中合金元素含量对电池阳极材料的性能产生了积极影响,使得合金的表面放电面积变大,放电均匀,更适合作为铝空气电池阳极材料。

关 键 词:铝空气电池  再生能源  铝合金阳极  氧化  显微结构  
收稿时间:2019-04-28

Electrochemical properties of Al-6061 and Al-7075 alloys as anode for aluminum air batteries
YANG Yagang,YU Xiaohua,ZHANG Lei,SHI Chunyang,ZHUANG Xiaodong,XIE Gang.Electrochemical properties of Al-6061 and Al-7075 alloys as anode for aluminum air batteries[J].Chemical Industry and Engineering Progress,2020,39(1):145-151.
Authors:YANG Yagang  YU Xiaohua  ZHANG Lei  SHI Chunyang  ZHUANG Xiaodong  XIE Gang
Affiliation:1. Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
2. Kunming Metallurgical Research Institute Co. , Ltd. , Kunming 650503, Yunnan, China
3. State Key Laboratory of Common Associated Non-ferrous Metal Resources Pressure Hydrometallurgy Technology, Kunming 650503, Yunnan, China
Abstract:The electrochemical properties of industrial 6061 aluminum alloy (6061), aviation 7075 aluminum alloy (7075) and pure aluminum as anode materials for aluminum air cell were studied. Electrochemical tests, constant-current discharge experiments and surface characterization were carried out to calculate the anodic energy densities of continuous constant discharge under different current densities of 40—120mA/cm2. The surface morphology of the electrode was studied by electron probe microscopy (EPMA), and the surface analysis was performed by using a spectral analyzer (WDS). The results showed that the alloying elements changed the surface characteristics of the battery during discharge. The content of 6061 alloy element has a positive effect on the performance of the battery anode material, making the surface larger and discharge more uniformly , which suggested that 6061 was more suitable to be used as an alloy anode.
Keywords:aluminum air battery  renewable energy  aluminum alloy anode  oxidation  microstructure  
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