Large electric-field-induced strain in B-site complex-ion (Fe0.5Nb0.5)4+-doped Bi1/2 (Na0.82K0.12)1/2TiO3 lead-free piezoceramics |
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Authors: | Pengyuan Fan Yangyang Zhang Bing Xie Yiwei Zhu Weigang Ma Chao Wang Bing Yang Jinlong Xu Jianzhong Xiao Haibo Zhang |
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Affiliation: | 1. College of Materials Science and Engineering, State Key Laboratory of Material Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074, PR China;2. Information Engineering Institute, Huanghe Science and Technology College, Zhengzhou 450000, PR China |
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Abstract: | In order to obtain a new system of (Bi1/2Na1/2)TiO3 (BNT) based lead-free incipient piezoceramics with large strain for practical applications of actuators, we investigated the effect of B-site complex-ion (Fe0.5Nb0.5)4+ (FN)-doped Bi1/2 (Na0.82K0.12)1/2TiO3 ceramics on the phase structure, dielectric, ferroelectric, piezoelectric and electric-field-induced strain properties. All samples exhibited single perovskite phase with pseudocubic symmetry. The room temperature electric-field-induced polarization (P-E) and strain (S-E) hysteresis loops indirectly illustrated ferroelectric-to-relaxor (FE-RE) phase transition. The increasing content of FN doping decreased the FE-RE phase transition temperature, TF-R to below room temperature and induced the reversible FE-RE phase transition, giving rise to a large strain of 0.462% with a normalized strain, d*33 of 660 pm/V at a critical composition of x = 5. A fluctuation of the dielectric curve for BNKT-5 mol% FN ceramics in the spectra around 80 °C before and after polarization suggested that the large strain response can be induced via delicate mixing of the FE and RE phase. |
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Keywords: | Lead-free piezoceramics Doped Large strain Phase transition Phase coexistence |
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