| 水分散体系中原子转移自由基聚合研究进展 |
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| 引用本文： | 王思瑶,雷良才,张俊,郭磊,李海英.水分散体系中原子转移自由基聚合研究进展[J].涂料工业,2011,41(2):64-68. |
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| 作者姓名： | 王思瑶 雷良才 张俊 郭磊 李海英 |
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| 作者单位： | 辽宁石油化工大学化学与材料科学学院,辽宁抚顺,113001 |
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| 摘 要： | 水分散体系中原子转移自由基聚合(ATRP)具有自由基聚合、乳液聚合和活性/可控聚合的优点,因此近年来关于水分散体系中ATRP的研究日益增多。本文综述了近年来水分散体系(包括乳液体系、细乳液体系、微乳液体系)中原子转移自由基聚合的研究进展,对应用在水分散体系中的几种ATRP反应机理做了简要介绍,包括正向AT-RP、反向ATRP(RATRP)、正向/反向同时进行的(SR&NI)ATRP、电子转移活化剂(AGET)ATRP,并对RATRP、SR&NI、ATRPAGET ATRP的优缺点进行了总结。
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| 关 键 词： | 原子转移自由基聚合(ATRP) 活性/可控聚合 水分散体系 |
Progress of Atom Transfer Radical Polymerization in Aqueous Dispersion Systems |
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| Wang Siyao,Lei Liangcai,Zhang Jun,Guo Lei,Li Haiyiny.Progress of Atom Transfer Radical Polymerization in Aqueous Dispersion Systems[J].Paint & Coatings Industry,2011,41(2):64-68. |
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| Authors: | Wang Siyao Lei Liangcai Zhang Jun Guo Lei Li Haiyiny |
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| Affiliation: | Wang Siyao,Lei Liangcai,Zhang Jun,Guo Lei,Li Haiyiny (School of Chemistry and Materials Science,Liaoning Shihua University,Funshun,Liaoning 113001,China) |
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| Abstract: | In aqueous dispersion system,atom transfer radical polymerization(ATRP) has the advantages of free radical process,emulsion polymerization and controlled/living polymerization.So in recent years,development of ATRP in aqueous dispersion system has received more attention.In this paper,recent developments of ATRP in aqueous dispersion system,such as emulsion,miniemulsion,microemulsion,have been introduced.Several mechanism for ATRP in aqueous dispersion system have been summarized,including normal ATRP,rever... |
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| Keywords: | atom transfer radical polymeization(ATRP) controlled/living polymeization equeous dispersion system |
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