Leaching kinetics of neodymium in sulfuric acid from E-scrap of NdFeB permanent magnet

The leaching kinetics of neodymium in NdFeB permanent magnet powder was analyzed for the purpose of recovery of neodymium in sulfuric acid (H₂SO₄) from E-scrap (electric scrap) of NdFeB permanent magnet powder treated by oxidation roasting to form a reactant. The reaction was conducted with H₂SO₄ concentrations ranging from 2.5 to 3.5M, a pulp density of 110.8 g/L, an agitation speed of 750 rpm, and a temperature range of 30 to 70 °C. After 4 h of leaching, the neodymium content in the E-scrap powders was completely converted into a neodymium sulfate (Nd₂(SO₄)₃) solution phase in H₂SO₄ in the condition of 70 °C and 3.0M H₂SO₄. Based on a shrinking core model with sphere shape, the leaching mechanism of neodymium was determined by the rate-determining step of the ash layer diffusion. Generally, the solubility of pure rare earth elements in H₂SO₄ is decreased with an increase in leaching temperatures. However, the leaching rate of the neodymium in E-scrap powders increased with the leaching temperatures in this study because the ash layer included in the E-scrap powder provided resistance against the leaching. Using the Arrhenius expression, the apparent activation energy values were determined to be 2.26 kJmol^?1 in 2.5M H₂SO₄ and 2.77 kJmol^?1 in 3.0 M H₂SO₄.