Synthesis and Characterization of V-HMS Employed for Catalytic Hydroxylation of Benzene |
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| Authors: | Sujiao Feng Supeng Pei Bin Yue Lin Ye Linping Qian Heyong He |
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| Affiliation: | 1. Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Laboratory of Advanced Materials, Fudan University, 200433, Shanghai, People’s Republic of China
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| Abstract: | V-HMS catalysts with different vanadium content have been prepared by co-synthesis method using dodecylamine as template. The isolated VO4 species are successfully incorporated into the framework of HMS for the samples with low vanadium content. The effect of various reaction conditions on the hydroxylation of benzene to phenol with H2O2 as oxidant in aqueous acetic acid solvent was investigated where the yield of phenol achieves 11.1% under the optimized condition. |
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