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A New Oxidation Catalyst System using Fluorous Cobalt(II) Species in Water-supercritical Carbon dioxide (C–H free environment) |
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| Authors: | Shik Chi Tsang Jie Zhu Kai Man K Yu |
| Affiliation: | (1) Surface and Catalysis Research Centre, School of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, UK |
| Abstract: | Stabilized water droplet dispersed in supercritical carbon dioxide fluid is demonstrated to be an excellent alternative solvent system to acetic acid for air oxidation of a number of alkyl aromatic hydrocarbons using Co(II) species at mild conditions. |
| Keywords: | supercritical carbon dioxide oxidation micro-emlusion alkyl aromatic hydrocarbons catalysis selectivity |
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