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变基质浓度下SBR亚硝化启动试验研究
引用本文:张昭,李冬,吴迪,王斌,高伟楠,曾辉平,张杰.变基质浓度下SBR亚硝化启动试验研究[J].现代化工,2012,32(4):84-89.
作者姓名:张昭  李冬  吴迪  王斌  高伟楠  曾辉平  张杰
作者单位:1. 北京工业大学水质科学与水环境恢复工程北京市重点实验室,北京,100124
2. 北京工业大学水质科学与水环境恢复工程北京市重点实验室,北京100124;哈尔滨工业大学城市水资源与水环境国家重点实验室,黑龙江哈尔滨150090
基金项目:国家自然科学基金(50878003);北京市自然科学基金(8092006);城市水资源与水环境国家重点实验室开放基金(QAK201005);国家科技重大专项—水专项(2008ZX07208-003-003)(2008ZX07420-004-BJUT001)(2008ZX07208-005-003);北京工业大学第九届研究生科技基金项目(ykj-2011-4764、ykj-2011-4765、ykj-2011-4766)
摘    要:采用SBR反应器,在低DO(<1.0 mg/L)及高氨氮浓度(220 mg/L)下,经过20周期(10 d)的连续运行,亚硝化率达到90%以上并且保持稳定。此后逐步降低氨氮浓度,深入研究6个不同水平下亚硝化效果和游离亚硝酸(FNA)及温度对亚硝化的影响。试验结果表明,高氨氮时,实施限时曝气且低DO、较高游离氨(FA)的联合抑制模式,低氨氮下,采取实时控制策略,避免过度曝气,经过130 d的运行,去除负荷稳定在0.301 kg NH 4+-N/(m3.d),污泥负荷稳定在0.374 kg NH4+-N/(kg MLSS.d),亚硝化率一直在95%以上,成功实现了低氨氮SBR亚硝化的启动。同时发现FNA对AOB的抑制具有可逆性,而缓慢升温对亚硝化效果影响不大。

关 键 词:SBR  亚硝化  亚硝化率  实时控制  氨氮去除负荷

Start-up of SBR nitritation under variable substrate concentrations
ZHANG Zhao , LI Dong , WU Di , WANG Bin , GAO Wei-nan , ZENG Hui-ping , ZHANG Jie.Start-up of SBR nitritation under variable substrate concentrations[J].Modern Chemical Industry,2012,32(4):84-89.
Authors:ZHANG Zhao  LI Dong  WU Di  WANG Bin  GAO Wei-nan  ZENG Hui-ping  ZHANG Jie
Affiliation:1,2(1.Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology,Beijing 100124,China;2.State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,Harbin 150090,China)
Abstract:The nitrite accumulation rate(NAR) is above 90% and stable after 20 continuous cycles(10 d) under low dissolved oxygen(DO) concentrations(<1.0 mg·L-1) and high ammonia concentrations(220 mg·L-1) in a sequencing batch reactor(SBR).Then gradually decreasing the ammonia concentrations,the nitritation effect of six different levels has been deeply studied.The influence of free nitrite acid(FNA) and temperature on nitritation is also investigated.The results show that taking the measures combined by limited aeration,the inhibition of low DO concentration and high free ammonia(FA) during high ammonia concentrations and real-time control for low ammonia concentrations to avoid excessive aeration,the ammonia removal rate and sludge removal rate are steady at 0.301 kg NH+4-N/(m3·d) and 0.374 kg NH+4-N/(kg MLSS·d),respectively,after 130 days’ operation.The NAR is steadily above 95%.SBR nitritation of low ammonia concentration is successfully started up.Meanwhile the inhibition of FNA to ammonia oxidation bacteria(AOB) is reversible,while slowly increasing in temperatures has very little effect on nitritation.
Keywords:SBR  nitritation  NAR  real-time control  ammonia removal rate
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