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拉伸对熔纺聚乙烯醇纤维结构形态的影响
引用本文:徐德根,阳知乾,李 林,刘建忠.拉伸对熔纺聚乙烯醇纤维结构形态的影响[J].合成纤维,2014(12):1-4.
作者姓名:徐德根  阳知乾  李 林  刘建忠
作者单位:(高性能土木工程材料国家重点实验室,江苏苏博特新材料股份有限公司,江苏 南京 211103)
基金项目:江苏省自然科学基金项目(BK20141012;BK2011835)
摘    要:采用含水的复合改性剂增塑聚乙烯醇(PVA),制备熔纺PVA纤维原丝。经冷拉伸3倍后,分别在160、220℃下进行热拉伸。研究了拉伸对纤维结构和表面、截面形貌的影响。结果表明:拉伸使纤维分子取向,结晶度升高;熔纺PVA纤维截面为圆形,拉伸后在纤维表面产生沿轴向的微孔,增加了纤维表面的粗糙度。

关 键 词:熔融纺丝  聚乙烯醇纤维  拉伸工艺  结构形态

Effect of Drawing Process on the Morphology of Melt-Spun Poly(vinyl alcohol) Fibers
XU De-gen,YANG Zhi-qian,LI Lin,LIU Jian-zhong.Effect of Drawing Process on the Morphology of Melt-Spun Poly(vinyl alcohol) Fibers[J].Synthetic Fiber in China,2014(12):1-4.
Authors:XU De-gen  YANG Zhi-qian  LI Lin  LIU Jian-zhong
Affiliation:(State Key Laboratory of High Performance Civil Engineering Materials, Jiangsu Sobute New Materials Co.Ltd., Nanjing 211103, Jiangsu, China)
Abstract:A hydrophilic plasticizer was used to modify the poly(vinyl alcohol)(PVA), and PVA precusor fi-bers were prepared by melt spinning process. PVA precusor fibers were cold-stretched by 3 times, and thenhot-stretched at 160 ℃ and 220 ℃ respectively. The influence of drawing process on fiber structure, sur-face and cross-section morphology was researched. Results showed that PVA fibers were stretched to pro-vide molecular orientation and increase crystallinity; the cross-section of PVA fibers was circular, micro-pores were generated micro-pores along the axial direction of PVA fibers surface after stretching; fiber sur-face roughness was also increased.
Keywords:melt spinning  poly(vinyl alcohol) fiber  drawing process  morphology
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