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Carbonato- and methanediolato(-2)-bridged nickel(II) coordination clusters from the use of N-salicylidene-4-methyl-o-aminophenol
Affiliation:1. Department of Chemistry, University of Patras, GR-265 04 Patras, Greece;2. Department of Chemistry, Cardiff University, Cardiff, Wales, CF10 3AT, UK;3. Institute of Nanoscience and Nanotechnology, NSCR “Demokritos”, GR-153 10 Aghia, Aghia Paraskevi Attikis, Greece;5. Institute of Chemical Engineering Sciences, Foundation for Research and Technology-Hellas, (FORTH/ICE-HT), Platani, P.O. Box 1414, GR-265 04 Patras, Greece;1. State Key Laboratory of Structural, Fujian Institute of Research in the Structure of Matter, Chinese Academy of Science, Fuzhou 350002, China;2. University of Chinese Academy of Sciences, Beijing 100039, China
Abstract:The use of N-salicylidene-4-methyl-o-aminophenol in nickel(II) pivalate chemistry has provided access to structurally and magnetically interesting {NiII6NaI4} and {NiII6} clusters possessing carbonato and methanediolato(-2) ligands, respectively, with novel coordination modes.
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