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Reference values of the chronoamperometric response at cylindrical and capped cylindrical electrodes
Authors:Dieter Britz  Ole Østerby
Affiliation:a Department of Chemistry, Aarhus University, 8000 Århus C, Denmark
b Department of Computer Science, Aarhus University, 8200 Århus N, Denmark
c Tyndall National Institute, Lee Maltings, Cork, Ireland
Abstract:This work provides accurate solutions of the cylinder flux function I(0,1;T), first solved by Jaeger and Clarke, which can serve as reference values for electrochemical amperometric diffusion limited currents at a cylinder, as well as heat fluxes under equivalent conditions (fixed temperature at the cylinder surface). For the capped cylinder of varying lengths, reference values of time-dependent electrochemical currents are provided. Steady state currents at capped cylinders are presented and a function is provided that fits the simulated values to within 1%. All of these are more accurate than in previous works.
Keywords:Computational electrochemistry  Finite difference digital simulation  Cylindrical electrodes  Reference currents  Cylindrical transport
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