| 微波催化合成2-噁唑烷酮 |
| |
| 引用本文： | 朱莹,赖玉娇,王亚军,南康立.微波催化合成2-噁唑烷酮[J].山东化工,2012,41(3):14-16. |
| |
| 作者姓名： | 朱莹 赖玉娇 王亚军 南康立 |
| |
| 作者单位： | 湖州师范学院生命科学学院,浙江湖州,313000 |
| |
| 基金项目： | 2011年度浙江省大学生科技创新活动计划 |
| |
| 摘 要： | 利用微波催化制备2-噁唑烷酮,分别考察了物料比、反应温度、反应时间等参数,得到最佳反应条件为:以N,N-二甲基甲酰胺为溶剂,微波功率400W,物料比n(尿素):n(乙醇胺):n(DMF)=1:1:3.42,在120℃下保温2h,然后升温至140℃保温0.5h,最后升温至150～160℃反应5h。在此条件下,2-噁唑烷酮收率达52.1%。
|
| 关 键 词： | 微波 2-噁唑烷酮 合成 |
Synthesis of 2 -Oxazolidinone by Microwave Irradiation |
| |
| ZHU Ying,LAI Yu-jiao,WANG Ya-jun,NAN Kang-li.Synthesis of 2 -Oxazolidinone by Microwave Irradiation[J].Shandong Chemical Industry,2012,41(3):14-16. |
| |
| Authors: | ZHU Ying LAI Yu-jiao WANG Ya-jun NAN Kang-li |
| |
| Affiliation: | ZHU Ying, LAI Yu -fiao, WANG Ira -jun, NAN Kang - li ( School of Life Sciences, Huzhou Teachers College, Huzhou 313000, China) |
| |
| Abstract: | 2- Oxazolidinone was prepared by microwave technology, and the optimal parameters such as ratio of reaction material, reaction temperature and reaction time were obtained. In the DMF solvent, yield of the product reached 52.1%, under the optimal conditions of microwave power 400W, the mole ratio of urea, ethanolamine and DMF was 1：1：3.42, insulated for 2h at 120 ℃, then heated to 140℃ for 0.5h, finally heated up to 150 - 160 ℃ for 5h. |
| |
| Keywords: | microwave irradiation 2 - oxazolidinone synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
