| 离子液体催化合成α－氨基膦酸酯 |
| |
| 引用本文： | 王亮,郑举敦,韦景怡.离子液体催化合成α－氨基膦酸酯[J].山西化工,2012,32(6):7-8,11. |
| |
| 作者姓名： | 王亮 郑举敦 韦景怡 |
| |
| 作者单位： | 中南民族大学化学与材料科学学院,湖北武汉,430074 |
| |
| 基金项目： | 中南民族大学大学生创新创业训练计划创新项目(KYCX120202Z) |
| |
| 摘 要： | 在室温、无溶剂条件下，离子液体BPy]H2PO4催化芳醛、芳胺和亚磷酸三乙酯发生缩合反应，合成了α-氨基膦酸酯。该方法具有产率高（61％－96％）、操作简便、催化剂对环境友好且可以重复使用的特点。
|
| 关 键 词： | 无溶剂 α-氨基膦酸酯 离子液体 合成 |
Synthesis of α-aminophosphonates catalyzed by ionic liquid |
| |
| WANG Liang,ZHENG Ju-dun,WEI Jing-yi.Synthesis of α-aminophosphonates catalyzed by ionic liquid[J].Shanxi Chemical Industry,2012,32(6):7-8,11. |
| |
| Authors: | WANG Liang ZHENG Ju-dun WEI Jing-yi |
| |
| Affiliation: | (College of Chemistry and Materials Science,South-Central University for Nationalities,Wuhan Hubei 430074,China) |
| |
| Abstract: | Synthesis of α-aminophosphonates catalyzed by ionic liquid BPy] H2PO4 with three component condensation of aromatic aldehydes, amine and tfiethyl phosphite at room temperature under solvent-free conditions is described. The remarkable features of this procedure are high yields （61% - 96% ）, use of recyclable and environmentally benign catalyst and simple experimental and work-up procedures. |
| |
| Keywords: | solven-free α-aminophosphonates ionic liquid synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
