Synthesis and characterization of needle-like BaAleO4:Eu,Dy phosphor via hydrothermal-homogeneous precipitation method |
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引用本文: | 张静娴,肖琴,刘应亮.Synthesis and characterization of needle-like BaAleO4:Eu,Dy phosphor via hydrothermal-homogeneous precipitation method[J].中国稀土学报(英文版),2013,31(4):342-346. |
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作者姓名: | 张静娴 肖琴 刘应亮 |
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作者单位: | Department of Chemistry,Jinan Universit |
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基金项目: | Project supported by National Natural Science Foundations of China (50872045, 21071063) |
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摘 要: | A needle-like Eu2+ and Dy3+ co-doped BaAl2O4 long-lasting phosphor was synthesized via a hydrothermal-homogeneous precipitation method assisted by cetyl trimethyl ammonium bromide(CTAB) as a template.The crystal structure,morphology and optical properties of the composites were characterized.XRD results showed that the single-phase BaAl2O4 was formed at 900 ℃ in an active carbon atmosphere,which was much lower than that prepared by traditional solid-state reaction method.Scanning electron microscopy(SEM) and transmission electron microscopy(TEM) observation revealed that the precursor had well-dispersed distribution and showed needle-like morphology with the average diameter of about 100 nm and the length up to 1 μm.The final product,BaAl2O4:Eu2+,Dy3+ phosphor,inherited the needle-like shape from precursor via adding the surfactant CTAB.After irradiation by ultraviolet radiation with 355 nm for 5 min,the phosphors emitted bluish green color long-lasting phosphorescence corresponding to the typical emission of Eu2+ ion.Both the photoluminescence spectra and luminance decay revealed that the phosphor had efficient luminescent and long-lasting properties.
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关 键 词: | long-lasting phosphor BaAl2O4:Eu2+ Dy3+ hydrothermal-homogeneous precipitation process luminescence rare earths |
收稿时间: | 29 October 2012 |
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