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Long-Lasting Properties of Rare Earth-Doped Y2O2S Phosphors
作者姓名:雷炳富  刘应亮  刘洁  唐功本  叶泽人  石春山
作者单位:[1]KeyLaboratoryofRareEarthChemistryandPhysics,ChangchunInstituteofAppliedChemistry,ChineseAcademyofSciences,Changchun130022,China [2]DepartmentofChemistry,JinanUniversity,Guangzhou510632,China
基金项目:国家自然科学基金,国家自然科学基金,Foundation from Key Laboratory of Rare Earth Chemistry and Physics of Changchun Institute of Applied Chemistry
摘    要:The aim of this presentation is to report a new result of afterglow materials. The Y2O2S:Ln^3 (Ln = Sm, Tm)phosphors show bright reddish orange and orange-yellow colors when excited by UV or visible light. The main spectroscopic characterizations of Sm^3 and Tm^3 in yttrium oxysulfide and their long-lasting phosphorescence were measured and discussed in this presentation. Their long-lasting phosphorescence can be seen by the naked eyes clearly for about one hour in the dark room after the irradiation light sources were removed. XRD and photoluminescence (PL) spectra as well as the luminance decay were used to characterize these long-lasting phosphorescence phosphors. The results of XRD indicate that the products synthesized through the flux fusion method under 1050℃ for 6 h have a good crystallization without any detectable amount of impurity phase. Both the PL spectra and luminance decay results reveal that these phosphors have efficient luminescent and good long-lasting properties. We believe that the experimental data gathered in our present work will be useful in finding some new long-lasting phosphors with different colors.

关 键 词:Y2O2S  稀土  掺杂  荧光材料  长余辉  发光性能  XRD

Long-Lasting Properties of Rare Earth-Doped Y2O2S Phosphors
Lei Bingfu ,Liu Yingliang ,Liu Jie ,Tang Gongben ,Ye Zeren ,Shi Chunshan.Long-Lasting Properties of Rare Earth-Doped Y2O2S Phosphors[J].Journal of Rare Earths,2004,22(1):75-78.
Authors:Lei Bingfu    Liu Yingliang  Liu Jie  Tang Gongben  Ye Zeren  Shi Chunshan
Affiliation:Lei Bingfu 1,2,Liu Yingliang 2,Liu Jie 1,Tang Gongben 1,Ye Zeren 1,Shi Chunshan 1*
Abstract:The aim of this presentation is to report a new result of afterglow materials. The Y2O2S∶Ln3 (Ln=Sm, Tm) phosphors show bright reddish orange and orange-yellow colors when excited by UV or visible light. The main spectroscopic characterizations of Sm3 and Tm3 in yttrium oxysulfide and their long-lasting phosphorescence were measured and discussed in this presentation. Their long-lasting phosphorescence can be seen by the naked eyes clearly for about one hour in the dark room after the irradiation light sources were removed. XRD and photoluminescence(PL) spectra as well as the luminance decay were used to characterize these long-lasting phosphorescence phosphors. The results of XRD indicate that the products synthesized through the flux fusion method under 1050 ℃ for 6 h have a good crystallization without any detectable amount of impurity phase. Both the PL spectra and luminance decay results reveal that these phosphors have efficient luminescent and good long-lasting properties. We believe that the experimental data gathered in our present work will be useful in finding some new long-lasting phosphors with different colors.
Keywords:optics  yttrium oxysulfide  thulium ion  samarium ion  afterglow  phosphors  rare earths
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