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冷却制度及物料配比对铝酸钙炉渣物化性能的影响
引用本文:佟志芳,廉丽莠,刘伟,谢森林.冷却制度及物料配比对铝酸钙炉渣物化性能的影响[J].江西有色金属,2011(4):7-11.
作者姓名:佟志芳  廉丽莠  刘伟  谢森林
作者单位:江西理工大学材料与化学工程学院;
基金项目:国家自然科学基金资助项目(50974064)
摘    要:通过XRD、激光粒度分析以及化学分析等手段系统研究了冷却制度及物料配比对铝酸钙炉渣物相组成、自粉性能以及炉渣中Al2O3的浸出性能等物化性能的影响.结果表明:炉渣熔体在降温速度为4~5℃/min的条件下,1200℃至1500℃是物相形成的关键性温度区间,1200℃以下,炉渣凝结结束,物相组成不变,形成的主要物相为Ca12Al14O33及r-Ca2SiO4.炉渣A/S(Al2O3/SiO2摩尔比)在0.5~1.5之间,C/A(CaO/Al2O3摩尔比)为1.5~1.8时,自粉及浸出性能良好,自粉率均在90%以上,Al2O3浸出率达80%以上.

关 键 词:冷却制度  物料配比  铝酸钙炉渣  物化性能

Effects of Cooling System and Raw Material Mixture Ratio on the Physical and Chemical Properties of Calcium Aluminum Slag
TONG Zhi-fang,LIAN Li-xiu,LIU Wei,XIE Sen-lin.Effects of Cooling System and Raw Material Mixture Ratio on the Physical and Chemical Properties of Calcium Aluminum Slag[J].Jiangxi Nonferrous Metals,2011(4):7-11.
Authors:TONG Zhi-fang  LIAN Li-xiu  LIU Wei  XIE Sen-lin
Affiliation:TONG Zhi-fang,LIAN Li-xiu,LIU Wei,XIE Sen-lin(Faculty of Material and Chemical Engineering,Jiangxi University of Science and Technology,Ganzhou 341000,China)
Abstract:The effects of cooling system and raw material mixture ratio on the phase composition,self-disintegrating behavior and Al2O3 leaching behavior were investigated by XRD,a laser particle size analyzer and chemical analyzer.The results indicated that the key temperature range was between 1200 and 1500 ℃ for phase composition with 5 ℃/min cooling rate,and the Slag condensation was over and the phase composition had no change under 1200 ℃,the main phases were Ca12Al14O33 and r-Ca2SiO4.The self-disintegrating and leaching behavior of the slag became better,and the self-disintegrating rate was more than 90 % and the leaching rate was more than 80 % when A/S(the quality ratio of Al2O3 to SiO2)was 0.5~1.5 and C/A(the molar ratio of CaO to Al2O3)was 1.5~1.8.
Keywords:cooling system  raw material mixture ratio  calcium aluminate slag  physical and chemical properties    
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