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油酸钠与十二烷基苯磺酸钠复配对白钨矿浮选的强化及机理研究
引用本文:王纪镇,印万忠,张宇轩,梁效,孙忠梅.油酸钠与十二烷基苯磺酸钠复配对白钨矿浮选的强化及机理研究[J].有色金属(选矿部分),2018(1):106-110.
作者姓名:王纪镇  印万忠  张宇轩  梁效  孙忠梅
作者单位:西安科技大学化学与化工学院;东北大学资源与土木工程学院;低品位难处理黄金资源综合利用国家重点实验室;
基金项目:陕西省自然科学基础研究计划(2017JQ5090),西安科技大学校级培育(201624)。
摘    要:通过浮选试验、动电位以及表面张力测定等方法研究了油酸钠(NaOL)与十二烷基苯磺酸(SDBS)复配对白钨矿浮选的强化作用。结果表明,NaOL与SDBS组合药剂的最佳添加顺序随矿浆p H值的改变而发生改变,在最佳的添加顺序下,NaOL与SDBS组合使用对白钨矿的捕收能力强于NaOL,而且还可消除或减弱方解石对白钨矿浮选的不利影响。机理研究表明,NaOL/SDBS组合药剂与白钨矿的相互作用强于NaOL与SDBS,且NaOL与SDBS之间存在相互作用,使NaOL/SDBS组合药剂的CMC小于NaOL与SDBS,这些是NaOL与SDBS复配强化白钨矿浮选的主要原因。

关 键 词:白钨矿  油酸钠  十二烷基苯磺酸钠  组合药剂  浮选
收稿时间:2017/7/3 0:00:00
修稿时间:2017/8/3 0:00:00

The mechanism and effect of mixed sodium oleate / sodiumSdodecyl benzeneSsulfonateSon the scheelite flotation
Authors:Jizhen Wang  Wanzhong Yin  Yuxuan Zhang  Xiao Liang and Zhongmei Sun
Abstract:The effect of mixed sodium oleate (NaOL) and sodiumSdodecyl benzeneSsulfonate (SDBS) on scheelite flotation was investigated through flotation tests, zeta potential measurements and surface tension measurements. The results indicated that the mixed NaOL/SDBS has a stronger collecting power for scheelite than NaOL, and the NaOL/SDBS could eliminated the adverse effect on scheelite flotation. The optimum addition order of mixed NaOL/SDBS was related to the pulp pH value. The results of mechanism study showed that the interaction between scheelite with NaOL/SDBS was stronger than that with NaOL and SDBS, and the interactive effect between NaOL and SDBS resulted in the CMC value of NaOL/SDBS was smaller than that of NaOL and SDBS, therefore, the collecting ability of NaOL/SDBS was stronger than that of NaOL and SDBS.
Keywords:scheelite  sodium oleate  sodiumSdodecyl benzeneSsulfonate  combined reagents  flotation
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