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偏高岭土混凝土的耐久性与水化特性分析
引用本文:宁波,刘苗苗,王文飞.偏高岭土混凝土的耐久性与水化特性分析[J].矿产综合利用,2022,43(6):49.
作者姓名:宁波  刘苗苗  王文飞
作者单位:1.陕西铁路工程职业技术学院 测绘与检测学院,陕西 渭南 714000
基金项目:国家自然科学基金资助项目(U1802243,41672317);陕西铁路工程职业技术学院中青年科技创新人才计划(KJRC201807); 陕西省渭南市2016 年科研计划项目(2016KYJ-1-3);陕西铁路工程职业技术学院(KY2015-69)
摘    要:为了得到不同偏高岭土掺量对混凝土物理、力学性能和水化特性的影响,开展了偏高岭土混凝土的基本物理力学实验和混凝土的水化性能实验。结果表明:适当掺加偏高岭土来代替混凝土水泥掺料,可以较好地提升混凝土的力学性能和工作性能。但是随着偏高岭土掺量的不断增大,混凝土内部的水泥含量会减少以及混凝土内部的化学结合水量减少。使得其水化放热量和放热速率均减小以及水化反应生成的氢氧化钙含量减少。通过结合偏高岭土水化后XRD图谱分析可知,在偏高岭土掺量为15%时钙矾石XRD图谱峰值最显著。这和前期得到混凝土力学性能达到较佳的偏高岭土掺量一致。 

关 键 词:化学结合水量    水化产物    水化放热速率    放热量    XRD图谱
收稿时间:2021-07-20

Analysis of Durability and Hydration Characteristics of Metakaolin Concrete
Affiliation:1.Shaanxi Railway Engineering Vocational and Technical College College of Surveying, Mapping and Testing, Weinan, Shaanxi, China2.Anyang Vocational and Technical College, Anyang, Henan, China3.College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, Hubei, China
Abstract:In order to obtain the effects of different amounts of metakaolin on the physical, mechanical properties and hydration characteristics of concrete, basic physical and mechanical tests of metakaolin concrete and concrete hydration performance tests were carried out. The results show that the proper addition of metakaolin instead of concrete cement admixture can better improve the mechanical properties and working performance of concrete. However, with the increasing content of metakaolin, the cement content inside the concrete will decrease and the chemically bound water inside the concrete will decrease. So that the heat and rate of hydration are reduced, and the content of calcium hydroxide generated by the hydration reaction is reduced. By combining the XRD pattern analysis of metakaolin after hydration, it can be known that the peak value of the XRD pattern of ettringite is the most significant when the content of metakaolin is 15%. This is consistent with the content of metakaolin that is obtained in the early stage to achieve the best mechanical properties of concrete. 
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