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磁性晶种对电镀污泥和红土镍矿酸浸液中铁铬的共去除研究
引用本文:杨宏斌,朱红斌,韦志伟,赵梦梦,李勇宾,何嘉靖,甘绍凤,李晓辉,唐富顺,张淑华.磁性晶种对电镀污泥和红土镍矿酸浸液中铁铬的共去除研究[J].矿冶工程,2018,38(6):107-111.
作者姓名:杨宏斌  朱红斌  韦志伟  赵梦梦  李勇宾  何嘉靖  甘绍凤  李晓辉  唐富顺  张淑华
作者单位:1.广西壮族自治区固体废物管理中心,广西 南宁 530028; 2.广西银亿新材料有限公司,广西 玉林 537624; 3.桂林理工大学 化学与生物工程学院,广西 桂林 541004
基金项目:广西科学研究与技术开发计划项目(桂科攻1598007-39)
摘    要:研究了磁性晶种对硫酸铁溶液、硫酸铬溶液、电镀污泥和红土镍矿酸浸液中铁铬的去除效果,并探讨了磁性晶种除铁铬的机制。结果表明,在电镀污泥和红土镍矿酸浸液中,当pH值高于2.5和温度80 ℃以上时磁性晶种能有效去除铁铬离子。当铁铬共存时,磁性晶种表面生成的含铁水合物具有更强的静电引力,促进了磁性晶种对铬离子的去除。

关 键 词:磁性晶种  酸浸液  除铁  除铬  电镀污泥  红土镍矿  铁离子  铬离子  
收稿时间:2018-06-17

Removal of Both Fe and Cr Ions by Magnetic Seed Crystal from Sulfuric Acid Leaching Lixivium of Electroplating Sludge and Laterite Nickel Ore
YANG Hong-bin,ZHU Hong-bin,WEI Zhi-wei,ZHAO Meng-meng,LI Yong-bin,HE Jia-jing,GAN Shao-feng,LI Xiao-hui,TANG Fu-shun,ZHANG Shu-hua.Removal of Both Fe and Cr Ions by Magnetic Seed Crystal from Sulfuric Acid Leaching Lixivium of Electroplating Sludge and Laterite Nickel Ore[J].Mining and Metallurgical Engineering,2018,38(6):107-111.
Authors:YANG Hong-bin  ZHU Hong-bin  WEI Zhi-wei  ZHAO Meng-meng  LI Yong-bin  HE Jia-jing  GAN Shao-feng  LI Xiao-hui  TANG Fu-shun  ZHANG Shu-hua
Affiliation:1.Guangxi Solid Waste Management Center, Nanning 530028, Guangxi, China; 2.Guangxi Yinyi Advanced Material Co Ltd, Yulin 537624, Guangxi, China; 3.College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, China
Abstract:Study was conducted on effect of removal of both iron and chromium ions from solution of ferric sulfate, solution of chromium sulfate, the leaching lixivium of electroplating sludge and laterite nickel ore by magnetic seed crystal, and the removal mechanism was discussed. It is shown that, as for the sulfuric acid leaching lixivium of electroplating sludge and laterite nickel ore, iron and chromium ions can be effectively removed by magnetic seed crystal at a temperature above 80 ℃, with pH value higher than 2.5. With the co-existence of iron and chromium irons, ferric hydrate generated on the surface of magnetic seed crystal has a stronger electrostatic attraction, which can facilitate the removal of chromium iron by magnetic seed crystal.
Keywords:magnetic seed crystal  acid-leaching lixivium  iron ion removal  chromium ion removal  electroplating sludge  laterite nickel ore  Fe ion  Cr ion  
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