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碱活化珍珠岩去除废水中Cd(Ⅱ)的研究
引用本文:姜林,胡慧敏,陈敏,张其武.碱活化珍珠岩去除废水中Cd(Ⅱ)的研究[J].矿产保护与利用,2021,41(3):173-178.
作者姓名:姜林  胡慧敏  陈敏  张其武
作者单位:武汉理工大学 资源与环境工程学院, 湖北 武汉 430070
摘    要:珍珠岩经高能球磨活化,并在球磨活化过程中添加Ca(OH)2以及CaCl2共磨,制备新型硅酸盐矿物材料。使用XRF、XRD、SEM/EDS等表征分析,以及Cd(Ⅱ)的吸附容量等对该吸附剂进行定性和定量的性能评价。结果表明,经过600 r/h的共磨后,吸附剂对Cd(Ⅱ)吸附量高达1 372.70 mg/g,同时,吸附后溶液的pH值为中性或弱碱性,比传统碱沉淀法显著降低。所制备的新型材料和制备工艺环境友好,原料廉价易得,为珍珠岩及其他硅酸盐矿物的活化利用提供了新思路。 

关 键 词:珍珠岩    高能球磨    Cd(Ⅱ)    吸附剂
收稿时间:2021-05-25

Study on the Removal of Cd(Ⅱ) in the Wastewater by Alkaline-activated Per-lite
JIANG Lin,HU Huimin,CHEN Min,ZHANG Qiwu.Study on the Removal of Cd(Ⅱ) in the Wastewater by Alkaline-activated Per-lite[J].Conservation and Utilization of Mineral Resources,2021,41(3):173-178.
Authors:JIANG Lin  HU Huimin  CHEN Min  ZHANG Qiwu
Affiliation:School of Resources and Environment Engineering, Wuhan University of Technology, Wuhan 430081, China
Abstract:Co-grinding perlite with calcium hydroxide and calcium chloride by high-energy ball mill was conducted to prepare novel silicate material. The adsorption characteristics of heavy metal by the new material were studied qualitatively and quantitatively by a set of analytical methods of XRF、XRD、SEM/EDS and evaluation of the adsorption capacity for Cd (Ⅱ). The results show that the adsorption capacity of Cd(Ⅱ) may reach 1 372.70 mg/g with the grinding time of 1h and the stirred speed of 600 r/min. Meanwhile, the final pH of solution after reaction is neutral or weak alkaline. It was greatly decreased compared with the common alkali precipitation. The preparing process and the product are environment-friendly, providing a new idea to activate and utilize perlite and other silicate ore tailings. 
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