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Yb3+掺杂氟铝酸盐玻璃的光谱性质
引用本文:李家成,李顺光,胡和方,干福熹.Yb3+掺杂氟铝酸盐玻璃的光谱性质[J].中国激光,2004,31(2):32-236.
作者姓名:李家成  李顺光  胡和方  干福熹
作者单位:1. 中国科学院上海光学精密机械研究所,上海,201800;中国科学院研究生院,北京,100039
2. 中国科学院上海光学精密机械研究所,上海,201800
摘    要:根据测得的Yb^3 离子在氟铝酸盐玻璃中的吸收光谱和荧光光谱,分析了Yb^3 离子在氟铝酸盐玻璃中的吸收和发射特性,计算了Yb^3 离子的发射截面,讨论了Yb^3 离子的荧光自吸收效应和浓度猝灭效应。结果表明,自吸收效应使Yb^3 离子实测发射截面与计算所得发射截面存在较大差异并使荧光强度降低,高掺杂时Yb^3 向杂质Er^3 的能量传递是导致浓度猝灭的另一重要原因。

关 键 词:光谱分析  氟铝酸盐玻璃  Yb^3+离子  光谱性质
收稿时间:2002/9/6

Spectroscopy of Yb3+-doped Fluoroaluminate Glasses
LI Jia-cheng ,LI Shun-guang ,HU He-fang ,GAN Fu-xi.Spectroscopy of Yb3+-doped Fluoroaluminate Glasses[J].Chinese Journal of Lasers,2004,31(2):32-236.
Authors:LI Jia-cheng    LI Shun-guang  HU He-fang    GAN Fu-xi
Affiliation:LI Jia-cheng 1,2,LI Shun-guang 1,HU He-fang 1,2,GAN Fu-xi 1,2 1Shanghai Institute of Optics and Fine Mechanics,The Chinese Academy of Sciences,Shanghai 201800,China 2Graduate School of the Chinese Academy of Sciences,Beijing 100039,China
Abstract:Absorption and emission properties of Yb 3+-doped fluoroaluminate glasses were analyzed according to the measured absorption and emission spectra. The emission cross section of Yb 3+ ions was calculated. The fluorescence reabsorption effect and concentration quenching effect of Yb 3+ ions were discussed. Difference between measured emission section and calculated emission section of Yb 3+ was caused by the reabsorption effect, which also decreased the fluorescence intensity of Yb 3+ ions. The energy transfer from Yb 3+ ions to Er 3+ ions was the second key factor leading to concentration quenching in heavily Yb 3+-doped fluoroaluminate glass.
Keywords:spectrum analysis  fluoroaluminate glass  Yb    3+ ions  spectroscopic properties
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