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氟化物和磷酸盐玻璃中Yb3+离子掺杂浓度对其发光及荧光寿命的影响
引用本文:张军杰,张龙,祁长鸿,林凤英,胡和方.氟化物和磷酸盐玻璃中Yb3+离子掺杂浓度对其发光及荧光寿命的影响[J].中国激光,1999,26(8):739-744.
作者姓名:张军杰  张龙  祁长鸿  林凤英  胡和方
作者单位:中国科学院上海光机所
摘    要:测量了不同掺杂浓度下Yb3+离子在氟化物及磷酸盐玻璃中的吸收光谱、发射光谱和Yb3+离子的荧光寿命,计算了Yb3+离子的发射截面σe,分析了Yb3+离子掺杂浓度对其发光强度和荧光寿命的影响。实验结果表明,Yb3+离子掺杂浓度较低时,对其荧光强度和荧光寿命没有显著影响。在高掺杂浓度时,发生了浓度猝灭效应,使Yb3+离子荧光强度降低,荧光寿命下降。对浓度猝灭效应产生的机理进行了分析和解释。

关 键 词:氟锆酸盐和磷酸盐玻璃,Yb~(3+)离子,掺杂浓度,发光和荧光寿命
收稿时间:1998/12/16

The Influence of Concentration of Yb3+ Ions on Luminescence and Fluorescence Lifetime in Fluorozirconate and Phosphate Glasses
Zhang Junjie,Zhang Long,Qi Changhong,Lin Fengying,Hu Hefang.The Influence of Concentration of Yb3+ Ions on Luminescence and Fluorescence Lifetime in Fluorozirconate and Phosphate Glasses[J].Chinese Journal of Lasers,1999,26(8):739-744.
Authors:Zhang Junjie  Zhang Long  Qi Changhong  Lin Fengying  Hu Hefang
Abstract:Absorption spectra, emission spectra and fluorescence lifetime were measured with different concentrations of Yb3+-doped, the emission cross section σe of Yb3+ was calculated. Dependence of luminescence intensity and fluorescence lifetime on concentration of Yb3+ was analyzed. No remarkable influence of concentration of Yb3+ ions on luminescence intensity and fluorescence lifetime was observed in the case of low level Yb3+ doped. Concentration quenching occurred when high level Yb3+ was doped. Luminescence intensity and fluorescence decreased because of it. The mechanism of concentration quenching was discussed and explained.
Keywords:fluorozirconate and phosphate glasses  Yb    3    ions  concentration doped  luminescence and luminescence lifetime  
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