Abstract: | Multilayered ZnO‐SnO2 heterostructure thin films consisting of ZnO and SnO2 layers are produced by alternating the pulsed laser ablation of ZnO and SnO2 targets, and their structural and field‐effect electronic transport properties are investigated as a function of the thickness of the ZnO and SnO2 layers. The performance parameters of amorphous multilayered ZnO‐SnO2 heterostructure thin‐film transistors (TFTs) are highly dependent on the thickness of the ZnO and SnO2 layers. A highest electron mobility of 43 cm2/V·s, a low subthreshold swing of a 0.22 V/dec, a threshold voltage of 1 V, and a high drain current on‐to‐off ratio of 1010 are obtained for the amorphous multilayered ZnO(1.5 nm)‐SnO2(1.5 nm) heterostructure TFTs, which is adequate for the operation of next‐generation microelectronic devices. These results are presumed to be due to the unique electronic structure of amorphous multilayered ZnO‐SnO2 heterostructure film consisting of ZnO, SnO2, and ZnO‐SnO2 interface layers. |