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Interfacial reactions and electrical properties of Hf/p-Si0.85Ge0.15
Authors:Ming-Shaw Chung  Ming-Jun Wang  Wen-Tai Lin  T C Chang  Y K Fang
Affiliation:(1) Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan 701, Republic of China;(2) Department of Physics, National Sun Yat-sen University, Kaohsiung, Taiwan, Republic of China;(3) Institute of Microelectronics, National Cheng Kung University, Tainan, Taiwan 701, Republic of China
Abstract:Interfacial reactions and electrical properties of Hf/p-Si0.85Ge0.15 as a function of the annealing temperature were studied. Hf3(Si1−xGe)2 and Hf(Si1−xGe)2 were initially formed at 500°C and 600°C, respectively. At temperatures above 400°C, Ge segregation out of the reacted layers associated with strain relaxation of the unreacted Si0.85Ge0.15 films appeared. At 780°C, agglomeration occurred in the Hf(Si1−xGex)2 films. All the as-deposited and annealed Hf/p-Si0.85Ge0.15 samples showed the formation of an ohmic contact. The lowest specific contact resistance around 10−5 ω cm2 could be obtained for the Hf3 (Si1−xGex)2 contacts to p-Si0.85Ge0.15 formed at 500°C. Below 500°C, the decrease of specific contact resistance with the annealing temperature is mainly caused by the formation of Hf3(Si1−xGex)2 and an interfacial Ge-rich layer between the Hf3(Si1−xGex)2 and unreacted Si0.85Ge0.15 films, while above 600°C, the increase of specific contact resistance may be due to the formation of Hf(Si1−xGex)2 and SiC as well as the roughness of the Hf(Si1−xGex)2 films.
Keywords:Hf  Si1−  xGex            ohmic contacts  Ge segregation
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