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Enhanced properties for visible-light-driven photocatalysis of Ag nanoparticle modified Bi2MoO6 nanoplates
Affiliation:1. Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;2. Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand;3. Department of Chemistry, Faculty of Science and Technology, Bansomdejchaopraya Rajabhat University, Bangkok 10600, Thailand;4. Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand;5. Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand;1. College of Chemistry, Chemical Engineering & Biotechnology, Donghua University, Shanghai 201620, China;2. Key Lab for Sport Shoes Upper Materials of Fujian Province (Fujian Huafeng New Material Co., Ltd.), Putian 351144, China;3. College of Environment and Resources, Guangxi Normal University, Guilin, Guangxi 541004, China;1. National Engineering Research Center for Colloidal Materials, Shandong University, Jinan 250100, PR China;2. Key Laboratory for Colloid and Interface Chemistry (Ministry of Education), Shandong University, Jinan 250100, PR China;3. School of Physics, Shandong University, Jinan 250100, PR China;1. State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum Beijing, No. 18 Fuxue Rd., Beijing 102249, PR China;2. Department of Materials Science and Engineering, College of Science, China University of Petroleum Beijing, No. 18 Fuxue Rd., Beijing 102249, PR China;1. College of Chemistry & Chemical Engineering, Yan’an University, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an 716000, China;2. Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany;1. Laboratory of Nanomaterials and Applied Nanotechnology, Institute of Physics, Federal University of Mato Grosso do Sul (UFMS), Av. Costa e Silva S/N, 79070-900, Campo Grande, MS, Brazil;2. Arizona State University, Mesa, AZ, 85212, United States;3. Institute of Chemical Sciences, University of Peshawar, POB,25120, Peshawar, Pakistan
Abstract:The visible light driven Bi2MoO6 photocatalyst doped with different contents of Ag nanoparticles was successfully synthesized by a combination of hydrothermal and sonochemical methods. The as-synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning and transmission electron microscopy (SEM and TEM) and UV–visible spectroscopy to investigate crystalline structure, morphology, composition and photocatalytic properties. XRD patterns and TEM images of the samples revealed pure phase orthorhombic Bi2MoO6 nanoplates without any detection of Ag dopant due to its low concentration and very tiny particle size. TEM images showed that Ag nanoparticles with the size of 10–15 nm were dispersed randomly on the surface of Bi2MoO6. The XPS analysis of Ag/Bi2MoO6 nanocomposites revealed the presence of additional metallic Ag. Photocatalytic activities of the Ag/Bi2MoO6 nanocomposites were evaluated by determining the degradation of rhodamine B (RhB) under visible light radiation. In this research, the 10 wt% Ag/Bi2MoO6 nanocomposites showed the best photocatalytic activity. The results suggest that the dispersion of Ag nanoparticles on the surface of Bi2MoO6 significantly enhances its photocatalytic activity.
Keywords:Photocatalyst  X-ray diffraction  Spectroscopy
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