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中孔结构对活性炭吸附卷烟烟气中有机物的影响
引用本文:宋磊,陈家元,冯利,邓文.中孔结构对活性炭吸附卷烟烟气中有机物的影响[J].环境科学学报,2014,34(2):349-354.
作者姓名:宋磊  陈家元  冯利  邓文
作者单位:1. 华侨大学化工学院, 厦门 361021;1. 华侨大学化工学院, 厦门 361021;2. 云和县环境监测站, 丽水 323600;3. 河北工业职业技术学院环境与化学工程系, 石家庄 050091;4. 西南民族大学旅游与历史文化学院, 成都 610041
基金项目:厦门市科技计划项目(No. 3502Z20113014);中央高校基本科研业务费专项资金(No. JB-ZR1150);华侨大学高层次人才科研启动基金(No. 11BS215)
摘    要:卷烟烟气中复杂化合物对大气环境的污染已经引起了全世界的关注.因此,本文以颗粒活性炭为原料,通过硝酸钙、水蒸气调控得到比表面积、微孔容量丰富且含有较高中孔率的介孔活性炭,研究了孔结构对三醋酸甘油酯和挥发性有机物吸附的影响.结果表明:活性炭对三醋酸甘油酯的吸附主要受到比表面积和微孔的影响,中孔对其吸附性能没有太明显的作用;中孔结构对苯、甲苯、丙酮的吸附可以起到明显的通道效应,大大提高了活性炭对挥发性有机物的去除能力.

关 键 词:活性炭  中孔  三醋酸甘油酯  挥发性有机物
收稿时间:2013/5/21 0:00:00
修稿时间:2013/7/30 0:00:00

Effects of mesopore of activated carbon on adsorption organic compounds from cigarette smoke
SONG Lei,CHEN Jiayuan,FENG Li and DENG Wen.Effects of mesopore of activated carbon on adsorption organic compounds from cigarette smoke[J].Acta Scientiae Circumstantiae,2014,34(2):349-354.
Authors:SONG Lei  CHEN Jiayuan  FENG Li and DENG Wen
Affiliation:1. School of Chemical Engineering, Huaqiao University, Xiamen 361021;1. School of Chemical Engineering, Huaqiao University, Xiamen 361021;2. Environmental Monitoring Station of Yunhe, Lishui 323600;3. Department of Environment and Chemical Engineering, Hebei College of Industry and Technology, Shijiazhuang 050091;4. School of Tourism and History, Southwest University for Nantionlities, Chengdu 610041
Abstract:Toxic compounds of cigarette smoke had induced series health risk and air pollution. The mesoporous activated carbon from granular microporous activated carbon was prepared by Ca(NO3)2 impregnated steam activation. The micropore size and surface area of adsorbent played a major role triacetion adsorption, rather than mesopores size and volume of adsorbent. Mesopore size and volume of adsorbent increased removal rate of benzene, toluene and acetone by transport pores for the adsorption.
Keywords:activated carbon  mesoporous  triacetin  volatile organic compounds(VOCs)
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