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天然膨润土还原吸附Cr(Ⅵ)
引用本文:罗平,田英.天然膨润土还原吸附Cr(Ⅵ)[J].化工环保,2013,33(1):6-9.
作者姓名:罗平  田英
作者单位:南京工业大学;环境学院,江苏;南京;210009
摘    要:以天然膨润土为吸附剂,还原吸附处理含Cr(Ⅵ)模拟废水。实验结果表明:以(NH42FeSO4为还原剂吸附效果最佳;在还原剂加入量为理论值的0.8倍、膨润土加入量为6 g/L、吸附时间为30 min、吸附温度为30 ℃、初始Cr(Ⅵ)质量浓度为1 mg/L的条件下,Cr(Ⅵ)去除率可达99.6%,处理后模拟废水中总铬质量浓度低至0.003 mg/L。天然膨润土对Cr(Ⅵ)的还原吸附符合准二级动力学模型及Freundlich等温吸附模型。

关 键 词:天然膨润土    还原  吸附  废水处理  
收稿时间:2013-03-14

Reduction Adsorption of Cr(Ⅵ) on Natural Bentonite
Luo Ping , Tian Ying.Reduction Adsorption of Cr(Ⅵ) on Natural Bentonite[J].Environmental Protection of Chemical Industry,2013,33(1):6-9.
Authors:Luo Ping  Tian Ying
Affiliation:College of Environment,Nanjing University of Technology,Nanjing Jiangsu 210009,China
Abstract:Natural bentonite was used as adsorbent in the reduction adsorption treatment of simulated Cr(Ⅵ)-containing wastewater. The experimental results show that:When (NH4)2FeSO4 is used as reducing agent,the adsorption effect is the best;When the dosage of reducing agent is 0.8 time of the theoretical value,the dosage of bentonite is 6 g/L,the adsorption time is 30 min,the adsorption temperature is 30 ℃ and the initial Cr(Ⅵ) mass concentration is 1 mg/L,the Cr(Ⅵ) removal rate can reach 99.6% and the total Cr mass concentration of the treated wastewater can be as low as 0.003 mg/L. The reduction adsorption of Cr(Ⅵ) on natural bentonite accords with pseudo-second-order kinetic model and Freundlich isothermal adsorption model.
Keywords:natural bentonite  chromium  reduction  adsorption  wastewater treatment
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