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注空气过程轻质原油低温氧化动力学
引用本文:侯胜明,刘印华,于洪敏,牛保伦,任韶然.注空气过程轻质原油低温氧化动力学[J].中国石油大学学报(自然科学版),2011,35(1):169-173.
作者姓名:侯胜明  刘印华  于洪敏  牛保伦  任韶然
作者单位:1. 中国石油大学,石油工程学院,山东,东营,257061
2. 中国石化,石油勘探开发研究院,北京,100083
基金项目:中国石油化工集团公司先导性科技项目(P06041)
摘    要:对于埋藏较深且注水困难的低渗透油藏,空气驱可作为二次采油方法.空气驱过程中地层内部分原油将和空气中的氧气发生低温氧化(LTO)反应生成烟道气(主要是N2、CO2)和油的氧化产物.通过分析轻质原油低温氧化机制,提出改进的低温氧化反应模型;采用小型台架反应器实验求取改进模型的动力学参数(Arrhenius活化能及频率因子)...

关 键 词:反应动力学  低温氧化  反应模型  低渗透油藏  注空气

Kinetics of low temperature oxidation of light oil in air injection process
HOU Sheng-ming,LIU Yin-hua,YU Hong-min,NIU Bao-lun,REN Shao-ran.Kinetics of low temperature oxidation of light oil in air injection process[J].Journal of China University of Petroleum,2011,35(1):169-173.
Authors:HOU Sheng-ming  LIU Yin-hua  YU Hong-min  NIU Bao-lun  REN Shao-ran
Affiliation:HOU Sheng-ming1,LIU Yin-hua1,YU Hong-min2,NIU Bao-lun1,REN Shao-ran1(1.College of Petroleum Engineering in China University of Petroleum,Dongying 257061,China,2.Research Institute of Exploration and Production,SINOPEC,Beijing 100083,China)
Abstract:Air injection process is an effective secondary oil recovery method for deep and light-oil reservoirs with very low permeability and poor water injection.During air injection,low temperature oxidation(LTO) may occur between a small fraction of reservoir oil and oxygen within injected air to produce flue gas(N2 and CO2) and oxygenated products.An improved LTO reaction model was established through analyzing light-oil LTO mechanisms.The kinetic parameters,in terms of the Arrhenius activation energy and reacti...
Keywords:reaction kinetics  low temperature oxidation  reaction model  low permeability reservoir  air injection  
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