| N-苯基氨基邻苯二甲酰亚胺衍生物的合成及初步杀虫活性 |
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| 引用本文： | 柳明,崔永亮,王毅,段又生,芮昌辉,王敏,刘尚钟.N-苯基氨基邻苯二甲酰亚胺衍生物的合成及初步杀虫活性[J].农药学学报,2009,11(1):51-54. |
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| 作者姓名： | 柳明 崔永亮 王毅 段又生 芮昌辉 王敏 刘尚钟 |
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| 作者单位： | 1.中国农业大学 应用化学系,农业部农药化学与应用技术重点开放实验室,北京 100193 |
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| 基金项目： | 国家自然科学基金，国家科技支撑计划 |
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| 摘 要： | 为寻找新型环境友好型杀虫剂,用取代苯酐与取代苯肼在冰乙酸中缩合,合成了11个未见杀虫活性报道的N-苯基氨基邻苯二甲酰亚胺衍生物,其中7个是新化合物。所有化合物结构均通过核磁共振氢谱及液质联机(LC-MSD)确认,并利用X-ray单晶衍射确认了 A02 的晶体结构。初步的杀虫活性测试结果表明,大部分化合物对小菜蛾具有一定的杀虫活性,其中化合物 A06 在600 g/mL下96 h的致死率达到84％。
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| 关 键 词： | N-苯基氨基邻苯二甲酰亚胺 合成 杀虫活性 |
| 收稿时间： | 2008/12/12 0:00:00 |
Synthesis and Preliminary Bioassay of N-Phenylaminophthalimide Derivatives |
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| LIU Ming,CUI Yong-liang,WANG Yi,DUAN You-sheng,RUI Chang-hui,WANG Min and LIU Shang-zhong.Synthesis and Preliminary Bioassay of N-Phenylaminophthalimide Derivatives[J].Chinese Journal of Pesticide Science,2009,11(1):51-54. |
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| Authors: | LIU Ming CUI Yong-liang WANG Yi DUAN You-sheng RUI Chang-hui WANG Min and LIU Shang-zhong |
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| Affiliation: | 1.Department of Applied Chemistry,China Agricultural University,Key Laboratory of Pesticide Chemistry and Application,Beijing 100193,China2.Institute of Plant Protection,China Academic of Agricultural Sciences,Beijing 100193,China |
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| Abstract: | In order to discover novel environmental friendly insecticide,11 no insecticidal activity reported N-phenylaminophthalimide derivatives were synthesized through condensation reaction of substituted phthalic anhydride and substituted phenylhydrazine in glacial acetic acid,and 7 among them were new compounds.The structures of all compounds were confirmed with 1H NMR & LC-MSD,and the crystal structure of A02 was characterized by X-ray crystal diffraction method.The preliminary bioassay showed that some compounds had certain insecticidal activity against Plutella xylostella Linnaeus at 600 μg/mL,and the lethal rate of compound A06 was 84% after 96 hours. |
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| Keywords: | N-phenylaminophthalimide derivatives synthesis biological activity |
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