| 双分子Salen金属催化剂的研究进展 |
| |
| 引用本文： | 杨薇,省聪聪,王益.双分子Salen金属催化剂的研究进展[J].云南民族学院学报(自然科学版),2013(6):394-398,402. |
| |
| 作者姓名： | 杨薇 省聪聪 王益 |
| |
| 作者单位： | 云南师范大学化学化工学院,云南昆明650500 |
| |
| 基金项目： | 云南省教育厅科学研究基金（220122020）. |
| |
| 摘 要： | 双分子Salen金属配合物通过双金属活性中心的协同作用能够有效地催化多种化学反应.双金属催化剂拥有2个金属催化中心，可以同时对底物进行活化，从而加快反应速度和提高反应选择性.某些情况下，有些不能发生的新反应通过这种策略也能很好地反应.对双分子Salen金属催化剂的设计原理、最有效的合成方法作了归纳总结，并讨论了其在催化方面的应用.
|
| 关 键 词： | 双分子Salen配合物 协同作用 反应选择性 |
Progress of organic reactions catalyzed by dimolecular salen complexes |
| |
| YANG Wei,SHENG Cong-cong,WANG Yi.Progress of organic reactions catalyzed by dimolecular salen complexes[J].Journal of Yunnan University of The Nationalities(Natural Sciences Edition),2013(6):394-398,402. |
| |
| Authors: | YANG Wei SHENG Cong-cong WANG Yi |
| |
| Affiliation: | (College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China) |
| |
| Abstract: | Bimolecular salen-metal complexes can effectively catalyze a variety of chemical reactions through the synergistic effect of bimetallic active center. Bimetallic catalysts have two central metal catalytic centers and thus can accelerate the reaction speed and improve reaction selectivity. In certain circumstances, some new reactions which will not occur under condition of monometallic catalyst can be smoothly incurred by such a strategy. Herein,this paper discusses the design principles and the most effective synthetic methods of bimolecular salen metal catalysts and their application in catalysis. |
| |
| Keywords: | bimolecular salen - metal complexes synergistic effect reaction selectivity |
| 本文献已被 维普 等数据库收录！ |
