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Alkyldibenzothiophenes: molecular tracers for filling pathway in oil reservoirs
作者姓名:WANGTieguan  HEFaqi  LIMeijun  HOUYong  GUOShuqi
作者单位:[1]KeyLaboratoryofPetroleumAccumulationMechanismoftheMinistryofEducation,UniversityofPetroleum,Beijing102249,China [2]Exploration&ProductionDepartment,SINOPEC,Beijing100029,China
摘    要:Based on the thermodynamic stability and hydrogen bond mechanisms, alkyldibenzothiophene molecular ratios, 4-/1-MDBT, 2,4-/1,4- and 4,6-/1,4-DMDBT, are used to characterize organic maturity and oil migration, which can act as molecular tracers for the filling orientation and pathway in oil reservoir. The application of aforesaid molecular parameters, in a Neogene sandstone reservoir of the XJ24-3 Oilfield, Zhujiangkou Basin and in an Ordovician carbonate reservoir of Karst pore-fissure-network type in the Tahe Oilfield, Tarim Basin, manifests that those ratios are reliable tracers compared with other molecular ratios, and thus, alkyldibezothiophene parameters may be used in a wide range of maturity, especially for high- to post-mature oil and severely biodegraded oil, both of which are short of effective molecular parameters.

关 键 词:油罐  填充路径  烷基联苯基噻吩  分子示踪剂  热力学稳定性  油气储存
收稿时间:2004-05-04
修稿时间:2004-10-09

Alkyldibenzothiophenes: molecular tracers for filling pathway in oil reservoirs
WANGTieguan HEFaqi LIMeijun HOUYong GUOShuqi.Alkyldibenzothiophenes: molecular tracers for filling pathway in oil reservoirs[J].Chinese Science Bulletin,2004,49(22):2399-2404.
Authors:Wang  Tieguan  He  Faqi  Li  Meijun  Hou  Yong  Guo  Shuqi
Affiliation:WANG Tieguan1,HE Faqi2,LI Meijun1,HOU Yong1 & GUO Shuqi1 1.Key Laboratory of Petroleum Accumulation Mechanism of the Minis- try of Education,University of Petroleum,Beijing 102249,China;2.Exploration & Production Department,SINOPEC,Beijing 100029,China
Abstract:Based on the thermodynamic stability and hy- drogen bond mechanisms, alkyldibenzothiophene molecular ratios, 4-/1-MDBT, 2,4-/1,4- and 4,6-/1,4-DMDBT, are used to characterize organic maturity and oil migration, which can act as molecular tracers for the filling orientation and path- way in oil reservoir. The application of aforesaid molecular parameters, in a Neogene sandstone reservoir of the XJ24-3 Oilfield, Zhujiangkou Basin and in an Ordovician carbonate reservoir of Karst pore-fissure-network type in the Tahe Oil- field, Tarim Basin, manifests that those ratios are reliable tracers compared with other molecular ratios, and thus, al- kyldibezothiophene parameters may be used in a wide range of maturity, especially for high- to post-mature oil and se- verely biodegraded oil, both of which are short of effective molecular parameters.
Keywords:oil reservoir  filling pathway  molecular tracers  diben- zothiophenes (DBTs)  methyldibenzothiophenes (MDBTs)  dimethy- ldibenzothiophenes (DMDBTs)  
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