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用1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮从硝酸介质中萃取钪
引用本文:徐岩冰,牛雁宁,丁华杰,杨维凡,袁双贵,肖永厚.用1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮从硝酸介质中萃取钪[J].科学技术与工程,2004,4(7):531-533.
作者姓名:徐岩冰  牛雁宁  丁华杰  杨维凡  袁双贵  肖永厚
作者单位:中国科学院近代物理研究所,兰州,730000
基金项目:国家自然科学基金(10075063,10175079),国家重点基础研究发展规划(G2000077400),中国科学院资助
摘    要:用1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮(PMBP)做萃取剂研究了从HNO3介质中痕量钪的溶剂萃取行为。发现在很低的酸度下,PMBP几乎可以定量地萃取痕量的钪。同时,也讨论了用PMBP从^18O离子辐照过的铀靶溶液中萃取分离钍时钪的沾污。

关 键 词:PMBP    萃取剂  示踪剂
文章编号:1671-1815(2004)07-0531-03
修稿时间:2004年3月9日

Extraction of Sc with 1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazolone from HNO3 Media
XU Yanbing,NIU Yanning,DING Huajie,YANG Weifan,YUAN Shuanggui,XIAO Yonghou Institute of Modern Physics,Chinese Academy of Sciences,Lanzhou.Extraction of Sc with 1-Phenyl-3-Methyl-4-Benzoyl-5-Pyrazolone from HNO3 Media[J].Science Technology and Engineering,2004,4(7):531-533.
Authors:XU Yanbing  NIU Yanning  DING Huajie  YANG Weifan~  YUAN Shuanggui  XIAO Yonghou Institute of Modern Physics  Chinese Academy of Sciences  Lanzhou
Affiliation:XU Yanbing,NIU Yanning,DING Huajie,YANG Weifan~1,YUAN Shuanggui,XIAO Yonghou Institute of Modern Physics,Chinese Academy of Sciences,Lanzhou 730000
Abstract:The solvent extraction behavior of the trace Sc was studied from nitric acid media with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP) as an extractant. It was found that the trace Sc can be extracted quantitatively into the organic phase from dilute nitric acid solutions. At the same time the contamination of the trace Sc in the thorium fraction separated from the solution of the uranium targets though PMBP extraction was discussed.
Keywords:PMBP  Sc  extractant  tracer
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